Molecular conductors based upon TTF-type donors and octahedral magnetic complexes

被引：43

作者：

Clemente-León, M

Coronado, E

Galán-Mascarós, JR

Giménez-Saiz, C

Gómez-García, CJ

Fabre, JM

机构：

[1] Univ Valencia, Dept Quim Inorgan, E-46100 Burjassot, Spain

[2] Univ Montpellier 2, Chim Organ Struct Lab, F-34095 Montpellier, France

来源：

SYNTHETIC METALS | 1999年 / 103卷 / 1-3期

关键词：

electrocrystallization; magnetic measurements; organic conductors based on radical cation salts; electron spin resonance;

D O I：

10.1016/S0379-6779(98)00239-2

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The synthesis, X-ray structures, electrical conductivities and magnetic properties (EPR and magnetic susceptibility) of several salts prepared with TTF-type donors and magnetic octahedral complexes are presented here.

引用

页码：2279 / 2282

页数：4

共 12 条

[1]

CARDUCCI MD, 1997, J AM CHEM SOC, V119, P1669

[2] Hybrid molecular materials formed by alternating layers of bimetallic oxalate complexes and tetrathiafulvalene molecules: Synthesis, structure, and magnetic properties of TTF4{Mn(H2O)(2)[Cr(ox)(3)](2)}center dot 14H(2)O [J].

Coronado, E ;

GalanMascaros, JR ;

GimenezSaiz, C ;

GomezGarcia, CJ ;

RuizPerez, C ;

Triki, S .

ADVANCED MATERIALS, 1996, 8 (09) :737-&

[3] Charge transfer salts based on polyoxometalates and seleno-substituted organic donors.: Synthesis, structure, and magnetic properties of (BEST)3H[PMo12O40]•CH3CN•CH2Cl2 (BEST = bis(ethylenediseleno)tetrathiafulvalene) [J].

Coronado, E ;

Galan-Mascaros, JR ;

Gimenez-Saiz, C ;

Gomez-Garcia, CJ ;

Falvello, LR ;

Delhaes, P .

INORGANIC CHEMISTRY, 1998, 37 (09) :2183-2188

[4] Polyoxometalate-based molecular materials [J].

Coronado, E ;

Gomez-Garcia, CJ .

CHEMICAL REVIEWS, 1998, 98 (01) :273-296

[5] Radical salts of the organic donor BET-TTF with polyoxometalate clusters [J].

Coronado, E ;

Galan-Mascaros, JR ;

Gimenez-Saiz, C ;

Gomez-Garcia, CJ ;

Rovira, C ;

Tarres, J ;

Triki, S ;

Veciana, J .

JOURNAL OF MATERIALS CHEMISTRY, 1998, 8 (02) :313-317

[6] STRUCTURE AND PROPERTIES OF TRIS[BIS(ETHYLENEDITHIO)TETRATHIAFULVALENIUM]TETRACHLOROCOPPER(II) HYDRATE, (BEDT-TTF)3CUCL4.H2O - 1ST EVIDENCE FOR COEXISTENCE OF LOCALIZED AND CONDUCTION ELECTRONS IN A METALLIC CHARGE-TRANSFER SALT [J].

DAY, P ;

KURMOO, M ;

MALLAH, T ;

MARSDEN, IR ;

FRIEND, RH ;

PRATT, FL ;

HAYES, W ;

CHASSEAU, D ;

GAULTIER, J ;

BRAVIC, G ;

DUCASSE, L .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (27) :10722-10729

[7] New BEDT-TTF salts with transition-metal containing anions [J].

Fat, P. ;

Graham, A.W. ;

Kepert, C.J. ;

Kurmoo, M. .

Synthetic Metals, 1995, 70 (1 -3 pt 2) :767-770

[8] New BETS conductors with magnetic anions (BETS equivalent to bis(ethylenedithio)tetraselenafulvalene) [J].

Kobayashi, H ;

Tomita, H ;

Naito, T ;

Kobayashi, A ;

Sakai, F ;

Watanabe, T ;

Cassoux, P .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (02) :368-377

[9] SUPERCONDUCTING AND SEMICONDUCTING MAGNETIC CHARGE-TRANSFER SALTS - (BEDT-TTF)(4)AFE(C(2)O4)(3)CENTER-DOT-C6H5CN (A=H2O, K, NH4) [J].

KURMOO, M ;

GRAHAM, AW ;

DAY, P ;

COLES, SJ ;

HURSTHOUSE, MB ;

CAULFIELD, JL ;

SINGLETON, J ;

PRATT, FL ;

HAYES, W ;

DUCASSE, L ;

GUIONNEAU, P .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (49) :12209-12217

[10]

OUAHAB L, 1989, ACTA CRYSTALLOGR C, V45, P371

← 1 2 →