Optical properties of the mechanochemically synthesized Cu2FeSnS4 (stannite) nanocrystals: Raman study

被引：7
|
作者：
Trajic, J. [1 ]
Romcevic, M. [1 ]
Petrovic, M. [1 ]
Gilic, M. [1 ]
Balaz, P. [2 ]
Zorkovska, A. [2 ]
Romcevic, N. [1 ]
机构：
[1] Univ Belgrade, Inst Phys, Belgrade 11080, Serbia
[2] Slovak Acad Sci, Inst Geotech, Kosice 04353, Slovakia
来源：
OPTICAL MATERIALS | 2018年 / 75卷
关键词：
Nanostructures; Optical properties; X-ray diffraction; Raman spectroscopy; CU2ZNSNS4; THIN-FILMS; NANOPARTICLES; SULFURIZATION; SPECTROSCOPY; PRECURSORS; DEPOSITION; KESTERITE; SNS;
D O I：
10.1016/j.optmat.2017.10.043
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The analysis of the vibrational properties of mechanochemically synthesized stannite Cu2FeSnS4 nano crystals has been performed. X-ray diffraction (XRD) and Raman spectroscopy are techniques used to characterize the crystal structure and compositional purity of stannite Cu2FeSnS4 nanoparticles. The detailed analysis of the experimental spectra has allowed us to determine the frequency and symmetry assignment of the main and weaker peaks. The milling time influence on synthesis stannite Cu2FeSnS4 from elemental precursors Cu, Fe, Sn and S is observed. Among the peaks that are characteristic for the stannite Cu2FeSnS4, we registered the modes of binary phases of FeS and SnS. The total disappearance of the binary phases of FeS and SnS is observed when the milling time is longer than 90 min. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码：314 / 318
页数：5
相关论文
共 50 条
  • [1] Far-infrared study of the mechanochemically synthesized Cu2FeSnS4 (stannite) nanocrystals
    Trajic, J.
    Romcevic, M.
    Paunovic, N.
    Curcic, M.
    Balaz, P.
    Romcevic, N.
    INFRARED PHYSICS & TECHNOLOGY, 2018, 90 : 66 - 69
  • [2] STUDY OF THE NATURE OF MELTING OF STANNITE CU2FESNS4
    NENASHEVA, SN
    KALININA, TA
    INORGANIC MATERIALS, 1986, 22 (01) : 17 - 20
  • [3] The crystal structure of stannite, CU2FeSnS4
    Brockway, LO
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1934, 89 (05): : 434 - 441
  • [4] Calorimetric determination of the standard enthalpy of formation of stannite, Cu2FeSnS4
    T. A. Stolyarova
    A. V. Baranov
    E. G. Osadchii
    Geochemistry International, 2018, 56 : 75 - 77
  • [5] Characterisation of the antiferromagnetic transition of Cu2FeSnS4, the synthetic analogue of stannite
    Caneschi, A
    Cipriani, C
    Di Benedetto, F
    Sessoli, R
    PHYSICS AND CHEMISTRY OF MINERALS, 2004, 31 (03) : 190 - 193
  • [6] EPR and SQUID magnetometry study of Cu2FeSnS4 (stannite) and Cu2ZnSnS4 (kesterite)
    G. P. Bernardini
    D. Borrini
    A. Caneschi
    F. Di Benedetto
    D. Gatteschi
    S. Ristori
    M. Romanelli
    Physics and Chemistry of Minerals, 2000, 27 : 453 - 461
  • [7] EPR and SQUID magnetometry study of Cu2FeSnS4 (stannite) and Cu2ZnSnS4 (kesterite)
    Bernardini, GP
    Borrini, D
    Caneschi, A
    Di Benedetto, F
    Gatteschi, D
    Ristori, S
    Romanelli, M
    PHYSICS AND CHEMISTRY OF MINERALS, 2000, 27 (07) : 453 - 461
  • [8] Calorimetric Determination of the Standard Enthalpy of Formation of Stannite, Cu2FeSnS4
    Stolyarova, T. A.
    Baranov, A. V.
    Osadchii, E. G.
    GEOCHEMISTRY INTERNATIONAL, 2018, 56 (01) : 75 - 77
  • [9] Synthesis and characterizations of quaternary Cu2FeSnS4 nanocrystals
    Yan, Chang
    Huang, Chun
    Yang, Jia
    Liu, Fangyang
    Liu, Jin
    Lai, Yanqing
    Li, Jie
    Liu, Yexiang
    CHEMICAL COMMUNICATIONS, 2012, 48 (20) : 2603 - 2605
  • [10] Characterisation of the antiferromagnetic transition of Cu2FeSnS4, the synthetic analogue of stannite
    A. Caneschi
    C. Cipriani
    F. Di Benedetto
    R. Sessoli
    Physics and Chemistry of Minerals, 2004, 31 : 190 - 193
12345