Ba8CoNb6O24:: A d0 dielectric oxide host containing ordered d7 cation layers 1.88 nm apart

被引：30

作者：

Mallinson, PM

Allix, MMB

Claridge, JB

Ibberson, RM

Iddles, DM

Price, T

Rosseinsky, MJ ^{[1
]}

机构：

[1] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England

[2] Rutherford Appleton Lab, CCLRC, Didcot OX11 0QX, Oxon, England

[3] Filtron Comtek, Div Ceram, Wolverhampton WV10 7DB, W Midlands, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 47期

基金：

英国工程与自然科学研究理事会;

关键词：

cations; dielectric materials; perovskite phases; transition-metal oxides; X-ray diffraction;

D O I：

10.1002/anie.200500135

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Following orders: The cobalt and niobium ions in Ba 8CoNb6O24 are completely ordered in the seven-layer repeat of hexagonal and cubic stacking. Such site-ordered solids may find application as microwave dielectric resonators, for example, in mobile telecommunications. In the structure shown, {CoO6} and {NbO 6} units are red and blue octahedra, respectively, and barium cations are black spheres. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：7733 / 7736

页数：4

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