Behavior of 3 mol% yttria-stabilized tetragonal zirconia polycrystal film prepared by slurry spin coating

被引:14
作者
Chen, Kongfa [1 ]
Tian, Yanting [1 ]
Lue, Zhe [1 ]
Ai, Na [1 ]
Huang, Xiqiang [1 ]
Su, Wenhui [1 ,2 ,3 ]
机构
[1] Harbin Inst Technol, Ctr Condensed Matter Sci & Technol, Harbin 150001, Peoples R China
[2] Jilin Univ, Dept Condensed Matter Phys, Changchun 130022, Peoples R China
[3] Int Ctr Mat Phys, Shenyang 110015, Peoples R China
关键词
3YSZ; Electrolyte film; Slurry spin coating; SOFC; OXIDE FUEL-CELLS; THIN-FILMS; YSZ FILMS; FABRICATION; ELECTROLYTE; PERFORMANCE; MEMBRANES; NIO/YSZ;
D O I
10.1016/j.jpowsour.2008.09.061
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A dense and uniform 3 mol% yttria-stabilized tetragonal zirconia polycrystal (3YSZ) electrolyte film of 6 mu m in thickness was fabricated by slurry spin coating on a porous NiO/3YSZanode substrate. Composite cathodes of La0.7Sr0.3MnO3 impregnated with Sm0.2Ce0.8O1.9 were fabricated on the 3YSZ films. A single cell produced in this way was tested at 700, 750 and 800 degrees C with hydrogen as fuel and stationary air as oxidant. Test results revealed an open-circuit voltage of 1.04V at 800 degrees C, and maximum power density of 551.895 and 1143 mW cm(-2) at 700,750 and 800 degrees C, respectively. Impedance spectra results demonstrated that the cell performance was determined by the polarization resistance of the cathode. (c) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:128 / 132
页数:5
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