Preparation and property of a novel soluble electron transport POSS-based hybrid material

被引：4
|
作者：
Wang, Xin [3 ,4 ]
Shen, Juan [3 ]
Wu, Jin Cui [3 ]
Fang, Min [3 ]
Xu, Hong Yao [1 ,2 ,3 ]
机构：
[1] Donghua Univ, Coll Mat Sci & Engn, Shanghai 201620, Peoples R China
[2] Donghua Univ, State Key Lab Chem Fibers & Polymer Mat, Shanghai 201620, Peoples R China
[3] Anhui Univ, Sch Chem & Chem Engn, Hefei 230039, Peoples R China
[4] Chizhou Univ, Sch Chem, Chizhou 247000, Peoples R China
来源：
CHINESE CHEMICAL LETTERS | 2008年 / 19卷 / 06期
关键词：
CV; Electron transport; Oxadiazole; POSS; Thermal stability;
D O I：
10.1016/j.cclet.2008.04.016
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel POSS-based organic/inorganic hybrid covalently attached at molecular level, 2-(4-(allyloxy)phenyl)-5-(4-(octyloxy)phenyl)-1,3,4-oxadiazole-POSS (6) ( abbreviated as oxadiazole-POSS) was synthesized by Pt(dcp) catalyst. The hybrid was soluble in common organic solvents such as CHCl3, toluene, C2H4Cl2, and THF. Its structures and properties were characterized and evaluated with FTIR, H-1 NMR, C-13 NMR, Si-29 NMR, EA, TGA, DSC, GPC, and CV, respectively. The results show that the novel hybrid possesses high thermal stability and good electron injection ability. (C) 2008 Hong Yao Xu. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.
引用
收藏
页码：634 / 638
页数：5
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