Metal-organic frameworks derived from chalcone dicarboxylic acid: New topological characters and initial catalytic properties

被引：5

作者：

Ma, Chixiao ^{[1
,2
]}

Pan, Wei ^{[2
]}

Zhang, Junyong ^{[2
]}

Zeng, Xianghua ^{[2
]}

Gong, Chunhua ^{[3
]}

Xu, Huiting ^{[4
]}

Shen, Runpu ^{[4
]}

Zhu, Dun-Ru ^{[1
]}

Xie, Jingli ^{[2
,4
]}

机构：

[1] Nanjing Tech Univ, Coll Chem Engn, Nanjing 211816, Peoples R China

[2] Jiaxing Univ, Coll Biol Chem Sci & Engn, Jiaxing 314001, Peoples R China

[3] Jiaxing Nanhu Univ, Coll Adv Mat Engn, Jiaxing 314001, Peoples R China

[4] Shaoxing Univ, Zhejiang Engn Res Ctr Fat Soluable Vitamin, Shaoxing 312000, Peoples R China

来源：

INORGANICA CHIMICA ACTA | 2022年 / 543卷

基金：

中国国家自然科学基金;

关键词：

Metal-organic frameworks; Topological; Heterogeneous catalysis; UNSUPPORTED ARGENTOPHILIC INTERACTIONS; COORDINATION POLYMERS; SILVER COMPLEXES; LIGAND; LUMINESCENT; CONSTRUCTION; ACTIVATION; CHEMISTRY; DESIGN; SERIES;

D O I：

10.1016/j.ica.2022.121166

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two metal-organic frameworks, [Ag2L(bpy()0.5)](n) (1) and [CoL(bpy)](n) (2), were successfully assembled through mixed-ligands strategy with different metal resource. Remarkably, both MOFs manifest multi-nuclear metal units as nodes and diverse topological structures. Compound 1 is an infinite two-dimensional layer structure with unsaturated four-nuclear silver unit nodes. While compound 2 exhibits a novel three-dimensional structure. The heterogeneous catalysis efficiency of the MOFs towards cycloaddition of N-methyl propargylamine with CO2 has been explored, and compound 1 displays higher catalytic activity derived from bare Lewis acid silver active site.

引用

页数：8

共 47 条

[1] Ligand design for functional metal-organic frameworks [J].

Almeida Paz, Filipe A. ;

Klinowski, Jacek ;

Vilela, Sergio M. F. ;

Tome, Joao P. C. ;

Cavaleiro, Jose A. S. ;

Rocha, Joao .

CHEMICAL SOCIETY REVIEWS, 2012, 41 (03) :1088-1110

[2]

Blatov V.A., 2006, IUCr CompComm Newsletter, V7, P4, DOI DOI 10.1039/B807165A

[3] Silver Clusters as Robust Nodes and π-Activation Sites for the Construction of Heterogeneous Catalysts for the Cycloaddition of Propargylamines [J].

Chang, Zhiduo ;

Jing, Xu ;

He, Cheng ;

Liu, Xin ;

Duan, Chunying .

ACS CATALYSIS, 2018, 8 (02) :1384-1391

[4] A trinuclear silver coordination polymer from a bipyridine bis-urea macrocyclic ligand and silver triflate [J].

Dawn, Sandipan ;

Salpage, Sahan R. ;

Smith, Mark D. ;

Sharma, Shiv K. ;

Shimizu, Linda S. .

INORGANIC CHEMISTRY COMMUNICATIONS, 2012, 15 :88-92

[5] OLEX2: a complete structure solution, refinement and analysis program [J].

Dolomanov, Oleg V. ;

Bourhis, Luc J. ;

Gildea, Richard J. ;

Howard, Judith A. K. ;

Puschmann, Horst .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2009, 42 :339-341

[6] Design and construction of coordination polymers with mixed-ligand synthetic strategy [J].

Du, Miao ;

Li, Cheng-Peng ;

Liu, Chun-Sen ;

Fang, Shao-Ming .

COORDINATION CHEMISTRY REVIEWS, 2013, 257 (7-8) :1282-1305

[7] UiO-66 derivatives and their composite membranes for effective proton conduction [J].

Feng, Lu ;

Hou, Hao-Bo ;

Zhou, Hong .

DALTON TRANSACTIONS, 2020, 49 (47) :17130-17139

[8] The Chemistry and Applications of Metal-Organic Frameworks [J].

Furukawa, Hiroyasu ;

Cordova, Kyle E. ;

O'Keeffe, Michael ;

Yaghi, Omar M. .

SCIENCE, 2013, 341 (6149) :974-+

[9] A new strategy for constructing a disulfide-functionalized ZIF-8 analogue using structure-directing ligand-ligand covalent interaction [J].

Gai, Yanli ;

Chen, Xitong ;

Yang, Huajun ;

Wang, Yanxiang ;

Bu, Xianhui ;

Feng, Pingyun .

CHEMICAL COMMUNICATIONS, 2018, 54 (85) :12109-12112

[10] Hydrothermal assembly, structures, topologies, luminescence, and magnetism of a novel series of coordination polymers driven by a trifunctional nicotinic acid building block [J].

Gu, Jin-Zhong ;

Liang, Xiao-Xiao ;

Cai, Yan ;

Wu, Jiang ;

Shi, Zi-Fa ;

Kirillov, Alexander M. .

DALTON TRANSACTIONS, 2017, 46 (33) :10908-10925

← 1 2 3 4 5 →