Sulfide oxidation by O2: Synthesis, structure and reactivity of novel sulfide-incorporated Fe(II) bis(imino)pyridine complexes

被引：9

作者：

Widger, Leland R. ^{[1
]}

Siegler, Maxime A. ^{[1
]}

Goldberg, David P. ^{[1
]}

机构：

[1] Johns Hopkins Univ, Dept Chem, Baltimore, MD 21218 USA

来源：

POLYHEDRON | 2013年 / 58卷

关键词：

Bis(imino)pyridine; Sulfide; Iron(II); Dioxygen; Non-heme Iron; Model Complexes; METHYL PHENYL SULFIDE; CYSTEINE DIOXYGENASE; MOLECULAR-OXYGEN; SPECTROSCOPIC CHARACTERIZATION; DEEP DESULFURIZATION; THIOETHER-OXIDATION; CRYSTAL-STRUCTURES; IRON; MODEL; MONONUCLEAR;

D O I：

10.1016/j.poly.2013.01.043

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The unsymmetrical iron(II) bis(imino)pyridine complexes [Fe-II(LN3SMe)(H2O)(3)](OTf)(2) (1), and [Fe-II(LN3SMe)Cl-2] (2) were synthesized and their reactivity with O-2 was examined. Complexes 1 and 2 were characterized by single crystal X-ray crystallography, LDI-MS, H-1 NMR and elemental analysis. The LN3SMe ligand was designed to incorporate a single sulfide donor and relies on the bis(imino)pyridine scaffold. This scaffold was selected for its ease of synthesis and its well-precedented ability to stabilize Fe(II) ions. Complexes 1 and 2 ware prepared via a metal-assisted template reaction from the unsymmetrical pyridyl ketone precursor 2-(O=CMe)-6-(2,6-(Pr-i(2)-C6H3N=CMe)-C5H3N. Reaction of 1 with O-2 was shown to afford the S-oxygenated sulfoxide complex [Fe(LN3S(O)Me)(OTf)](2+) (3), whereas compound 2, under the same reaction conditions, afforded the corresponding sulfone complex [Fe(LN3S(O-2)Me)Cl](2+) (4). (C) 2013 Elsevier Ltd. All rights reserved.

引用

页码：179 / 189

页数：11

共 34 条

[31] Synthesis and characterization of two manganese(II) complexes containing di(4-pyridyl)sulfide (4-DPS) ligand: The effects of the counter ion and of the weak non-covalent interactions in the crystal structures of [Mn(4-DPS)4(H2O)2](ClO4)2.H2O and {[Mn(4-DPS)2(NCS)2]•2H2O}n
Marinho, Maria Vanda
Yoshida, Maria Irene
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De Oliveira, Luiz Fernando C.
Diniz, Renata
Machado, Flavia C.
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[32] Novel one-dimensional cyano-bridged chain complexes [Ln(bet)2(H2O)3Fe(CN)6In (Ln = Nd, Pr, Sm, Gd; bet = betaine):: synthesis, crystal structure and magnetochemistry
Yan, B
Wang, HD
Chen, ZD
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[33] Synthesis, structure and reactivity of sulfur-rich [Fe(L1)(L2)('tpS4')] complexes with rigid [Fe('tpS4'] cores and σ-π Co-ligands ('tpS4'2-=1,2-bis(2-mercaptophenylthio)phenylene(2-); L1, L2=CO, PR3, NO)
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[34] Reactivity of carbonyl stabilized ylides with Zeise's salt. Synthesis, characterization of mono- and bis-ylidic Pt(II) derivatives and X-ray crystal structure of the {PtCl2[C(H)COCH3(PPh(2)-o-C6H4)]}[PPh(3)CH(2)COCH(3)] complex
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Zanotto, L
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