Crystal structure of (NH4)4[(UO2)2(C2O4)3(NCS)2] • 2H2O

被引：0
|
作者：
Artem'eva, MY
Dolgushin, FM
Antipin, MY
Serezhkina, LB
Serezhkin, VN
机构：
[1] Samara State Univ, Samara 443011, Russia
[2] Russian Acad Sci, Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2004年 / 49卷 / 03期
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D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The crystal structure of (NH4)(4)[(UO2)(2)(C2O4)(3)(NCS)(2)](.)2H(2)O (I) was studied by X-ray diffraction. The crystals are triclinic; the unit cell parameters are a = 7.786(5) Angstrom, b = 8.839(4) Angstrom, c = 9.465(3) Angstrom, alpha = 108.30(3)degrees, beta = 92.18(4)degrees, gamma = 92.73(4)degrees, space group P (1) over bar, Z = 1, R = 0.0263. The main structural unit in crystals of I are binuclear groups of the [(UO2)(2)(C2O4)(3)(NCS)(2)](4-) composition belonging to the A(2)K(02)B(2)(01)M(2)(1) (A = UO22+) crystal-chemical group of uranyl complexes. The uranium-containing complexes are combined in a three-dimensional framework by ammonium ions and a system of hydrogen bonds involving outer-sphere water molecules.
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页码：369 / 372
页数：4
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