Azoarenes with Opposite Chiral Configurations: Light-Driven Reversible Handedness Inversion in Self-Organized Helical Superstructures

被引：87
|
作者：
Li, Yannian [1 ,2 ]
Wang, Mengfei [1 ,2 ]
White, Timothy J. [3 ]
Bunning, Timothy J. [3 ]
Li, Quan [1 ,2 ]
机构：
[1] Kent State Univ, Inst Liquid Crystal, Kent, OH 44242 USA
[2] Kent State Univ, Chem Phys Interdisciplinary Program, Kent, OH 44242 USA
[3] Air Force Res Lab WPAFB, Mat & Mfg Directorate, Dayton, OH 45433 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 34期
关键词：
chiral conflict; handedness inversion; liquid crystals; self-organized helices; supramolecular chemistry; CIRCULAR-DICHROISM SPECTROSCOPY; LIQUID-CRYSTALS; CONFORMATIONAL-ANALYSIS; CHOLESTERIC INDUCTION; BLUE REFLECTION; SWITCHES; GREEN; RED; DERIVATIVES;
D O I：
10.1002/anie.201303786
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
On the other hand: Azoarene compounds with axially chiral binaphthyl units of the same and opposite chiral configurations were doped into achiral liquid crystals (LCs). They were found to efficiently induce self-organized helical superstructures, which could be reversibly tuned by light irradiation using trans-cis photoisomerization to change the handedness of the helix (see scheme) in LC hosts. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：8925 / 8929
页数：5
相关论文
共 17 条
  • [1] Dynamic handedness inversion of self-organized helical superstructures enabled by novel thermally stable light-driven chiral hydrazone switches
    Chen, Jingyu
    Wang, Zichen
    Yu, Yuexin
    Huang, Jun
    Chen, Xinyu
    Du, Tongji
    Song, Xinyue
    Yuan, Haiyang
    Zhou, Shuai
    Hu, Xiang-Guo
    Zeng, Xingping
    Zhong, Shengliang
    Lan, Ruochen
    CHEMICAL SCIENCE, 2024, 15 (41) : 17041 - 17048
  • [2] Photodynamic Chiral Molecular Switches with Thermal Stability: From Reflection Wavelength Tuning to Handedness Inversion of Self-Organized Helical Superstructures
    Li, Yannian
    Xue, Chenming
    Wang, Mengfei
    Urbas, Augustine
    Li, Quan
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (51) : 13703 - 13707
  • [3] Luminescence-Driven Reversible Handedness Inversion of Self-Organized Helical Superstructures Enabled by a Novel Near-Infrared Light Nanotransducer
    Wang, Ling
    Dong, Hao
    Li, Yannian
    Liu, Rui
    Wang, Ye-Fu
    Bisoyi, Hari Krishna
    Sun, Ling-Dong
    Yan, Chun-Hua
    Li, Quan
    ADVANCED MATERIALS, 2015, 27 (12) : 2065 - 2069
  • [4] Reversible Handedness Inversion and Circularly Polarized Light Reflection Tuning in Self-Organized Helical Superstructures Using Visible-Light-Driven Macrocyclic Chiral Switches
    Wang, Hao
    Tang, Yuqi
    Bisoyi, Hari Krishna
    Li, Quan
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2023, 62 (08)
  • [5] Optically reconfigurable chiral microspheres of self-organized helical superstructures with handedness inversion
    Wang, Ling
    Chen, Dong
    Gutierrez-Cuevas, Karla G.
    Bisoyi, Hari Krishna
    Fan, Jing
    Zola, Rafael S.
    Li, Guoqiang
    Urbas, Augustine M.
    Bunning, Timothy J.
    Weitz, David A.
    Li, Quan
    MATERIALS HORIZONS, 2017, 4 (06) : 1190 - 1195
  • [6] Reversible Visible-Light Tuning of Self-Organized Helical Superstructures Enabled by Unprecedented Light-Driven Axially Chiral Molecular Switches
    Wang, Yan
    Urbas, Augustine
    Li, Quan
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (07) : 3342 - 3345
  • [7] Reversible Circularly Polarized Reflection in a Self-Organized Helical Superstructure Enabled by a Visible-Light-Driven Axially Chiral Molecular Switch
    Wang, Hao
    Bisoyi, Hari Krishna
    Urbas, Augustine M.
    Bunning, Timothy J.
    Li, Quan
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2019, 141 (20) : 8078 - 8082
  • [8] Efficient visible-light full-color tuning of self-organized helical superstructures enabled by fluorinated chiral switches
    Qin, Lang
    Gu, Wei
    Chen, Yingying
    Wei, Jia
    Yu, Yanlei
    RSC ADVANCES, 2018, 8 (68): : 38935 - 38940
  • [9] Stimuli-Driven Control of the Helical Axis of Self-Organized Soft Helical Superstructures
    Bisoyi, Hari Krishna
    Bunning, Timothy J.
    Li, Quan
    ADVANCED MATERIALS, 2018, 30 (25)
  • [10] Frequency-Driven Self-Organized Helical Superstructures Loaded with Mesogen-Grafted Silica Nanoparticles
    Gutierrez-Cuevas, Karla G.
    Wang, Ling
    Zheng, Zhi-gang
    Bisoyi, Hari K.
    Li, Guoqiang
    Tan, Loon-Seng
    Vaia, Richard A.
    Li, Quan
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (42) : 13090 - 13094
12