Azide-bridged Cd(II) 1D coordination polymer with Cd13 nano-crown-like cluster

被引：13
作者：
Bai, Shi-Qiang [1 ,2 ,3 ]
Fang, Chen-Jie [2 ,3 ,4 ]
He, Zheng [2 ,3 ]
Gao, En-Qing [5 ]
Yan, Chun-Hua [2 ,3 ]
Hor, T. S. Andy [1 ,6 ]
机构：
[1] ASTAR, Inst Mat Res & Engn, Singapore 117602, Singapore
[2] Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China
[3] Peking Univ, Coll Chem & Mol Engn, PKU HKU Joint Lab Rare Earth Mat & Bioinorgan Che, Beijing 100871, Peoples R China
[4] Capital Med Univ, Sch Chem Biol & Pharmaceut, Beijing 100069, Peoples R China
[5] E China Normal Univ, Dept Chem, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China
[6] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore
来源：
CRYSTENGCOMM | 2013年 / 15卷 / 04期
基金：
中国国家自然科学基金;
关键词：
SCHIFF-BASE; CADMIUM(II) COMPLEXES; CRYSTAL-STRUCTURES; STRUCTURAL-CHARACTERIZATION; LUMINESCENCE PROPERTIES; SPONTANEOUS RESOLUTION; DI-2-PYRIDYL KETONE; METAL-COMPLEXES; NI-II; LIGANDS;
D O I：
10.1039/c2ce26525g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel polymeric one-dimensional 2-acetylpyridine-supported cadmium(II)-azide shows tridecanuclear Cd-13 crown-like clusters with defective supercubane cores, in which the azide ligands show mu-1,1- and mu-1,1,1-N-3 bridging modes.
引用
收藏
页码：650 / 653
页数：4
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