Selective hydrogenation of higher saturated carboxylic acids to alcohols using a ReOx-Pd/SiO2 catalyst

被引：104

作者：

Takeda, Yasuyuki ^{[1
]}

Nakagawa, Yoshinao ^{[1
]}

Tomishige, Keiichi ^{[1
]}

机构：

[1] Tohoku Univ, Sch Engn, Dept Appl Chem, Aoba Ku, Sendai, Miyagi 9808579, Japan

来源：

CATALYSIS SCIENCE & TECHNOLOGY | 2012年 / 2卷 / 11期

关键词：

HYDROGENOLYSIS; GLYCEROL; BIOMASS; RHENIUM;

D O I：

10.1039/c2cy20302b

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Higher fatty alcohols were synthesized in high yield (>92%) by direct hydrogenation of fatty acids catalyzed by ReOx-Pd/SiO2. High catalytic performance of ReOx-Pd/SiO2 can be generated by the synergy between ReOx and Pd. Preferential adsorption of the carboxylic acid to alcohols prohibited the overreaction of alcohols to alkanes.

引用

页码：2221 / 2223

页数：3

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