A strategy for scalable synthesis of Li4Ti5o12/reduced graphene oxide toward high rate lithium-ion batteries

被引:53
作者
Ni, Haifang [1 ]
Song, Wei-Li [1 ]
Fan, Li-Zhen [1 ]
机构
[1] Univ Sci & Technol Beijing, Inst Adv Mat & Technol, Being 100083, Peoples R China
关键词
Lithium-ion batteries; Lithium titanate; Reduced graphene oxide; Anode materials; ELECTROCHEMICAL PERFORMANCE; ANODE MATERIAL; LI4TI5O12; NANOSHEETS; STORAGE; NANOSTRUCTURES; DEPOSITION; ELECTRODE;
D O I
10.1016/j.elecom.2013.12.016
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Li4Ti5O12/reduced graphene oxide (RGO) composites were prepared via a simple strategy. The as-prepared composites present Li4Ti5O12 nanoparticles uniformly immobilized on the RGO sheets. The Li4Ti5O12/RGO composites possess excellent electrochemical properties with good cycle stability and high specific capacities of 154 mAh g(-1) (at 10C) and 149 mAh g(-1) (at 20C), much higher than the results found in other literatures. The superior electrochemical performance of the Li4Ti5O12/RGO composites is attributed to its unique hybrid structure of conductive graphene network with the uniformly dispersed Li4Ti5O12 nanopartides. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:1 / 4
页数:4
相关论文
共 28 条
[1]   General synthesis of carbon-coated nanostructure Li4Ti5O12 as a high rate electrode material for Li-ion intercalation [J].
Cheng, Liang ;
Yan, Jing ;
Zhu, Guan-Nan ;
Luo, Jia-Yan ;
Wang, Cong-Xiao ;
Xia, Yong-Yao .
JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (03) :595-602
[2]   Single-Step Synthesis of Nanosized Titanium-Based Oxide/Carbon Nanotube Composites by Electrospray Deposition and Their Electrochemical Properties [J].
Doi, Takayuki ;
Miwa, Yohei ;
Iriyama, Yasutoshi ;
Abe, Takeshi ;
Ogumi, Zempachi .
JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (18) :7719-7722
[3]   Br-Doped Li4Ti5O12 and Composite TiO2 Anodes for Li-ion Batteries: Synchrotron X-Ray and in situ Neutron Diffraction Studies [J].
Du, Guodong ;
Sharma, Neeraj ;
Peterson, Vanessa K. ;
Kimpton, Justin A. ;
Jia, Dianzeng ;
Guo, Zaiping .
ADVANCED FUNCTIONAL MATERIALS, 2011, 21 (20) :3990-3997
[4]   PREPARATION OF GRAPHITIC OXIDE [J].
HUMMERS, WS ;
OFFEMAN, RE .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (06) :1339-1339
[5]   Highly Improved Rate Capability for a Lithium-Ion Battery Nano-Li4Ti5O12 Negative Electrode via Carbon-Coated Mesoporous Uniform Pores with a Simple Self-Assembly Method [J].
Kang, Eunae ;
Jung, Yoon Seok ;
Kim, Gi-Heon ;
Chun, Jinyoung ;
Wiesner, Ulrich ;
Dillon, Anne C. ;
Kim, Jin Kon ;
Lee, Jinwoo .
ADVANCED FUNCTIONAL MATERIALS, 2011, 21 (22) :4349-4357
[6]   Li4Ti5O12/reduced graphite oxide nano-hybrid material for high rate lithium-ion batteries [J].
Kim, Hyun-Kyung ;
Bak, Seong-Min ;
Kim, Kwang-Bum .
ELECTROCHEMISTRY COMMUNICATIONS, 2010, 12 (12) :1768-1771
[7]   Silicon nanoparticles-graphene paper composites for Li ion battery anodes [J].
Lee, Jeong K. ;
Smith, Kurt B. ;
Hayner, Cary M. ;
Kung, Harold H. .
CHEMICAL COMMUNICATIONS, 2010, 46 (12) :2025-2027
[8]   Spinel Li4Ti5O12 Nanotubed for Energy Storage Materials [J].
Lee, Soon Chang ;
Lee, Sang Man ;
Lee, Jae Won ;
Lee, Jin Bae ;
Lee, Sang Moon ;
Han, Sang Sup ;
Lee, Hee Cheon ;
Kim, Hae Jin .
JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (42) :18420-18423
[9]   Layered double hydroxide nano- and microstructures grown directly on metal substrates and their calcined products for application as Li-ion battery electrodes [J].
Liu, Jinping ;
Li, Yuanyuan ;
Huang, Xintang ;
Li, Guangyun ;
Li, Zikun .
ADVANCED FUNCTIONAL MATERIALS, 2008, 18 (09) :1448-1458
[10]   Graphene-Confined Sn Nanosheets with Enhanced Lithium Storage Capability [J].
Luo, Bin ;
Wang, Bin ;
Li, Xianglong ;
Jia, Yuying ;
Liang, Minghui ;
Zhi, Linjie .
ADVANCED MATERIALS, 2012, 24 (26) :3538-3543