The effect of depressant sesbania gum on the flotation of a talc-containing scheelite ore

被引:23
|
作者
Zhao, Kaile [1 ,2 ]
Gu, Guohua [1 ]
Wang, Xiaohui [2 ]
Yan, Wu [2 ]
Hu, YeHuai [1 ]
机构
[1] Cent S Univ, Sch Minerals Proc & Bioengn, Changsha, Hunan, Peoples R China
[2] Chinese Acad Geol Sci, Inst Multipurpose Utilizat Mineral Resources, Chengdu, Sichuan, Peoples R China
来源
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T | 2019年 / 8卷 / 01期
基金
中国国家自然科学基金;
关键词
Scheelite; Talc; Sesbania gum; Sulfonated oleic acid; Adsorption mechanism; ADSORPTION; CALCITE;
D O I
10.1016/j.jmrt.2018.01.006
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Sodium silicate (SS) has been widely used as a depressant for the scheelite flotation. However, low selectivity and large amount of SS remains a tough problem. In this work, the effect of depressant sesbania gum (SGM) on the flotation of a talc-containing scheelite ore was investigated through pure mineral flotation and run-of-mine ore flotation tests. The flotation tests showed that the selective separation between scheelite and talc was achieved using a new reagent schedule, i.e., a lower dosage of SGM (80 mg/L) and a new collector of sulfonated oleic acid (SNaOL, 40 mol/L) at pH 9.0. A concentrate with WO3 grade of 52.0% and recovery of 78.4% was achieved by the run-of-mine ore batch flotation test. In addition, the mechanism of the selective separation was investigated by zeta-potential measurements, FTIR spectra and XPS analyses, which demonstrated that SNaOL absorbed more strongly and selectively on the "scheelite + SGM" surface than on the "talc + SGM" surface, while SGM could more selectively interact on the talc surface than on the scheelite surface. SGM absorbed on the talc surface by chemical adsorption between the Mg/Si atom of the talc surface and OH group in SGM molecule. (C) 2018 Brazilian Metallurgical, Materials and Mining Association. Published by Elsevier Editora Ltda.
引用
收藏
页码:14 / 21
页数:8
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