Molecular engineering for efficient and selective iron porphyrin catalysts for electrochemical reduction of CO2 to CO

被引：60

作者：

Ambre, Ram B. ^{[1
]}

Daniel, Quentin ^{[1
]}

Fan, Ting ^{[2
]}

Chen, Hong ^{[1
]}

Zhang, Biaobiao ^{[1
]}

Wang, Lei ^{[1
]}

Ahlquist, Marten S. G. ^{[2
]}

Duan, Lele ^{[1
]}

Sun, Licheng ^{[1
,3
]}

机构：

[1] KTH Royal Inst Technol, Dept Chem, S-10044 Stockholm, Sweden

[2] KTH Royal Inst Technol, Sch Biotechnol, Div Theoret Chem & Biol, S-10691 Stockholm, Sweden

[3] Dalian Univ Technol, DUT KTH Joint Educ & Res Ctr Mol Devices, State Key Lab Fine Chem, Dalian 116012, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 100期

基金：

瑞典研究理事会; 中国国家自然科学基金;

关键词：

CARBON-DIOXIDE REDUCTION; LOCAL PROTON SOURCE; ELECTROCATALYTIC REDUCTION; COMPLEXES; ELECTROREDUCTION; HYDROGENATION; CONVERSION; FORMATE; RHENIUM; SYSTEM;

D O I：

10.1039/c6cc08099e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Iron porphyrins Fe-pE, Fe-mE, and Fe-oE were synthesized and their electrochemical behavior for CO2 reduction to CO has been investigated. The controlled potential electrolysis of Fe-mE gave exclusive 65% Faradaic efficiency (FE) whereas Fe-oE achieved quasi-quantitative 98% FE (2% H-2) for CO production.

引用

页码：14478 / 14481

页数：4

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