A snapshot of a coordination polymer self- assembly process: the crystallization of a metastable 3D network followed by the spontaneous transformation in water to a 2D pseudopolymorphic phase

被引：21

作者：

Bataille, Thierry ^{[3
]}

Costantino, Ferdinando ^{[1
,2
]}

Ienco, Andrea ^{[4
]}

Guerri, Annalisa ^{[5
]}

Marmottini, Fabio ^{[1
,2
]}

Midollini, Stefano ^{[4
]}

机构：

[1] Univ Perugia, Dipartimento Chim, I-06123 Perugia, Italy

[2] Univ Perugia, CEMIN, I-06123 Perugia, Italy

[3] Univ Rennes 1, CNRS, Sci Chim Rennes UMR 6226, F-35042 Rennes, France

[4] ICCOM CNR, I-50019 Florence, Italy

[5] Univ Florence, Dipartimento Chim, I-50019 Florence, Italy

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 47期

关键词：

D O I：

10.1039/b813222d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A metastable copper(II) 3D hybrid with 4,4'-bipyridine (4,4'-bipy) and P,P'-diphenylethylenediphosphinate (pc(2)p(2-)) undergoes a spontaneous, quantitative, transformation to a stable 2D polymorphic species either spontaneously in water, or after thermal dehydration followed by hydration.

引用

页码：6381 / 6383

页数：3

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