Erbium(III) triflate: A valuable catalyst for the synthesis of aldimines, ketimines, and enaminones

被引：61
作者：
Dalpozzo, R
De Nino, A
Nardi, M
Russo, B
Procopio, A
机构：
[1] Univ Calabria, Dipartimento Chim, I-87030 Arcavacata Di Rende, Cs, Italy
[2] Magna Graecia Univ Catanzaro, Dipartimento Sci Farmacobiol, I-88021 Roccelletta Di Borgia, Cz, Italy
来源：
SYNTHESIS-STUTTGART | 2006年 / 07期
关键词：
imines; enaminones; erbium triflate; Lewis acids; catalysis;
D O I：
10.1055/s-2006-926378
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Aldimines, ketimines, and enaminones can be obtained under erbium(III) triflate catalysis. The reaction mechanism is that typical of imine synthesis. The role of the catalyst is demonstrated for the synthesis of aromatic imines. In contrast to CeCl3/NaI addition to unsaturated aldehydes, which results in Michael addition, no Michael adduct was observed under erbium(III) triflate catalysis.
引用
收藏
页码：1127 / 1132
页数：6
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