Brilliant opportunities across the spectrum

被引:7
作者
Evans, John [1 ]
机构
[1] Univ Southampton, Sch Chem, Southampton SO17 1BJ, Hants, England
[2] Diamond Light Source, Didcot OX11 0DE, Oxon, England
关键词
D O I
10.1039/b604369k
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Third generation synchrotron light sources provide stable, tuneable light of energy up to the hard X-ray region. The gain of a trillion in brightness as compared to a conventional laboratory X-ray source transforms the opportunities for establishing structure-function relationships. The light may be quasi-continuous or pulsed, have controllable polarisation and have coherence lengths larger than the sample size. The high brightness provides a basis for adding time and spatial resolution to X-ray scattering and spectroscopy. It may also be used to identify very specific information about the magnetic properties of atoms within materials, element specific vibrations, and local structural descriptions identified with chemical speciation. More demanding scattering and diffraction problems can be solved such as weakly scattering materials, large unit cells and structural entities. The high collimation of the source also provides enhanced spectroscopic and diffraction resolution that gives more insight into molecular, extended and supramolecular structures. The length scales can be bridged from the atomic up to that of visible light microscopy and buried features within materials can be observed with the appropriate energy. With an increased emphasis on ease of use, such capabilities are open to exploitation for chemical challenges.
引用
收藏
页码:3045 / 3058
页数:14
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