Observation of significant steric, valence and polarization effects and their interplay: a modified theory for electric double layers

被引：12

作者：

Liu, Xinmin ^{[1
]}

Yang, Gang ^{[1
]}

Li, Hang ^{[1
]}

Tian, Rui ^{[1
]}

Li, Rui ^{[1
]}

Jiang, Xianjun ^{[1
]}

Ni, Jiupai ^{[1
]}

Xie, Deti ^{[1
]}

机构：

[1] Southwest Univ, Coll Resources & Environm, Chongqing Key Lab Soil Multiscale Interfacial Pro, Chongqing 400715, Peoples R China

来源：

RSC ADVANCES | 2014年 / 4卷 / 03期

关键词：

EXCHANGE-REACTIONS; ELECTROLYTES; ADSORPTION; PARTICLES; SOIL;

D O I：

10.1039/c3ra44984j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Presented electric double layer theory achieves comparable results with experiments by including steric, polarization and valence effects and is applicable to all ions contrasting the classical theory only to hydrogen ions, which thus capably describes the selective adsorption on charged surfaces and is expected to clarify specific ion effects.

引用

页码：1189 / 1192

页数：4

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