New understanding and controllable synthesis of silica hollow microspheres with size-tunable penetrating macroporous shells as a superior support for polystyrene hydrogenation catalysts

被引:31
作者
Pan, Deng [1 ,2 ]
Shi, Gang [2 ]
Zhang, Teng [2 ]
Yuan, Pei [1 ]
Fan, Yu [2 ]
Bao, Xiaojun [2 ]
机构
[1] China Univ Petr, State Key Lab Heavy Oil Proc, Beijing 102249, Peoples R China
[2] China Univ Petr, China Natl Petr Corp, Key Lab Catalysis, Beijing 102249, Peoples R China
基金
中国国家自然科学基金;
关键词
PERFORMANCE LIQUID-CHROMATOGRAPHY; BIOMEDICAL APPLICATIONS; COMPETITIVE ADSORPTION; ANIONIC SURFACTANTS; FORMATION MECHANISM; DIATOMACEOUS-EARTH; TEMPLATE SYNTHESIS; FAB-MS; SPHERES; MACROMOLECULES;
D O I
10.1039/c3ta11824j
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Silica hollow microspheres (SHMs) with size-tunable penetrating macropores from 250 nm to 560 nm are prepared by a water/oil/water ternary phase emulsion system. Furthermore, the thus-obtained SHMs can serve as a superior support to fabricate supported palladium catalysts for the hydrogenation of bulky polystyrene molecules.
引用
收藏
页码:9597 / 9602
页数:6
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