Manganese-Catalyzed Cross-Coupling of Thiols with Aryl Iodides

被引:52
作者
Liu, Tsung-Jui [1 ]
Yi, Chih-Lun [1 ]
Chan, Chien-Ching [1 ]
Lee, Chin-Fa [1 ]
机构
[1] Natl Chung Hsing Univ, Dept Chem, Taichung 402, Taiwan
关键词
aryl iodide; cross-coupling; N ligands; manganese; thiol; ONE-POT SYNTHESIS; C-S; BOND FORMATION; GRIGNARD-REAGENTS; HALIDES; EFFICIENT; SULFIDES; SUBSTITUTION; DISULFIDES; FLUORIDES;
D O I
10.1002/asia.201300045
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A manganese-catalyzed cross-coupling reaction of thiols with aryl iodides, furnishing aryl thioethers in good to excellent yields has been reported; the system shows good functional group tolerance and enables the sterically demanding aryl iodides to couple with thiols.
引用
收藏
页码:1029 / 1034
页数:6
相关论文
共 72 条
[1]   Rhodium-catalyzed reductive coupling of disulfides and diselenides with alkyl halides, using hydrogen as a reducing agent [J].
Ajiki, K ;
Hirano, M ;
Tanaka, K .
ORGANIC LETTERS, 2005, 7 (19) :4193-4195
[2]  
Alami M, 1998, SYNLETT, P325
[3]  
[Anonymous], **DROPPED REF**
[4]  
[Anonymous], 2009, ANGEW CHEM INT ED, V48, P5691
[5]  
[Anonymous], 2008, ANGEW CHEM INT ED, V47, P2880
[6]  
[Anonymous], 2003, ANGEW CHEM INT EDIT
[7]  
[Anonymous], 2009, ANGEW CHEM
[8]  
[Anonymous], 2011, ANGEW CHEM INT ED, V50, P10406
[9]  
[Anonymous], 2008, ANGEW CHEM INT ED, V47, P6954
[10]   Transition-metal-free Sonogashira-type coupling reactions in water [J].
Appukkuttan, P ;
Dehaen, W ;
Van der Eycken, E .
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2003, 2003 (24) :4713-4716