Titanium/aluminum diborides in composites produced in the cBN-TiC-Al system by reaction sintering under high pressure

被引:7
作者
Bezhenar, M. P. [1 ]
Bozhko, S. A. [1 ]
Garbuz, T. O. [1 ]
Bilyavyna, N. M. [2 ]
Markiv, V. Ya. [2 ]
机构
[1] Natl Acad Sci Ukraine, Bakul Inst Superhard Mat, UA-04074 Kiev, Ukraine
[2] Taras Shevchenko Kiev Natl Univ, UA-01033 Kiev, Ukraine
关键词
cubic boron nitride; sintering; high pressure; X-ray structure analysis; titanium diboride; aluminum diboride;
D O I
10.3103/S1063457608050067
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
It has been found by X-ray diffraction and structure analyses that in the reaction sintering of cubic boron nitride composites from the cBN+8 % Al+26 % TiC mixture at high pressure and temperature (4.2 GPa, 1750 K) in the binding ceramics composition in addition to AlN, there forms a Ti (x) Al1-x B-2y N2(1-y) solid solution, in which titanium and aluminum atoms generate a skeleton, whose composition is close to the equimolar one and boron and nitrogen atoms are distributed randomly in graphite-like networks.
引用
收藏
页码:317 / 325
页数:9
相关论文
共 19 条
  • [1] BEZHENAR MP, 2007, SVERKHTVERDYE MAT, P27
  • [2] BEZHENAR MP, 2007, PORODORAZRUSHAYUSHCH, P184
  • [3] BEZHENAR NP, 2007, FIZIKA TEKHNIKA VYSO, V17, P86
  • [4] BEZHENAR NP, 2007, COPOVIDI NAN UKRAINY, P76
  • [5] BEZHENAR NP, 1996, SVERKHTVERDYE MAT, P54
  • [6] BEZHENAR NP, 2008, SVERKHTVERDYE MAT, P92
  • [7] BORIMSKII AI, 2003, SVERKHTVERDYE MAT PO, V1, P29
  • [8] On the electronic and structural properties of aluminum diboride Al0.9B2
    Burkhardt, U
    Gurin, V
    Haarmann, F
    Borrmann, H
    Schnelle, W
    Yaresko, A
    Grin, Y
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 2004, 177 (02) : 389 - 394
  • [9] DRACHINSKII AS, 2006, ELEKTRONNAYA MIKROSK, P147
  • [10] GARBUZ TO, 2007, PORODORAZRUSHAYUSHCH, P320