Pd-Catalyzed Oxidative Arylation of Cinnamylphosphonates: An Efficient Synthesis of (Z)-Alkenylphosphonates

被引：3

作者：

Lee, Hyun Seung

Lim, Cheol Hee

Lee, Hyun Ju

Kim, Jae Nyoung ^{[1
]}

机构：

[1] Chonnam Natl Univ, Dept Chem, Kwangju 500757, South Korea

来源：

BULLETIN OF THE KOREAN CHEMICAL SOCIETY | 2012年 / 33卷 / 11期

基金：

新加坡国家研究基金会;

关键词：

Palladium; Oxidative arylation; Cinnamylphosphonate; Alkenylphosphonates; Morita-Baylis-Hillman adducts; HIGHLY SELECTIVE ARYLATION; C-H FUNCTIONALIZATION; HECK REACTIONS; METALATION-DEPROTONATION; ARYLBORONIC ACIDS; STEREOSELECTIVE-SYNTHESIS; FORMAL SYNTHESIS; ALLYLIC ESTERS; ARYL BROMIDES; BETA-HYDRIDE;

D O I：

10.5012/bkcs.2012.33.11.3817

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Various alkenylphosphonates were prepared via the palladium-catalyzed oxidative arylation of cinnamylphosphonates with arenes. The regioselectivity during the beta-H elimination of the corresponding alkylpalladium intermediate was governed most likely by steric factors.

引用

收藏

页码：3817 / 3822

页数：6

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