Design of Magnetic Polyoxometalates for Molecular Spintronics and as Spin Qubits

被引：27

作者：

Baldovi, J. J. ^{[1
]}

Cardona-Serra, S. ^{[1
]}

Gaita-Arino, A. ^{[1
]}

Coronado, E. ^{[1
]}

机构：

[1] Univ Valencia, Inst Ciencia Mol ICMol, Paterna, Spain

来源：

ADVANCES IN INORGANIC CHEMISTRY, VOL 69: POLYOXOMETALATE CHEMISTRY | 2017年 / 69卷

关键词：

MIXED-VALENCE POLYOXOMETALATE; INELASTIC NEUTRON-SCATTERING; SINGLE-ION MAGNETS; AB-INITIO CALCULATIONS; ELECTRIC-FIELD CONTROL; LANTHANIDE COMPLEXES; QUANTUM COHERENCE; KEGGIN STRUCTURE; EXCHANGE INTERACTIONS; RATIONAL DESIGN;

D O I：

10.1016/bs.adioch.2016.12.003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In the past decades, POMs have been used as minimal models in Molecular Magnetism, since they are a convenient playing ground to study fundamental phenomena such as anisotropic magnetic exchange and electron transfer. Now they have jumped to the stage of the rational design of single-ion magnets and are being considered as test subjects for simple experiments in Single-Molecule Spintronics and Molecular Quantum Computing. This chapter contains an overview of recent results that demonstrate the potential of POMs in these emerging fields.

引用

页码：213 / 249

页数：37

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