Recognition-directed orthogonal self-assembly of polymers and nanoparticles on patterned surfaces

被引：89
|
作者：
Xu, H [1 ]
Hong, R [1 ]
Lu, TX [1 ]
Uzun, O [1 ]
Rotello, VM [1 ]
机构：
[1] Univ Massachusetts, Dept Chem, Amherst, MA 01003 USA
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 10期
关键词：
D O I：
10.1021/ja058686o
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We demonstrate the patterning of silica substrates with thymine (Thy-PS) and positively charged N-methylpyridinium (PVMP) polymers using photolithography and the subsequent orthogonal modification of these surfaces using diaminopyridine-functionalized polystyrene (DAP-PS) and carboxylate-derivatized CdSe/ZnS core-shell nanoparticles (COO-NP) through diamidopyridine-thymine three-point hydrogen bonding and pyridinium-carboxylate electrostatic interactions, respectively. This two-component orthogonal surface modification was accomplished in a self-sorting, single-step fashion, providing a versatile tool for the rapid and efficient creation of complex materials. Copyright © 2006 American Chemical Society.
引用
收藏
页码：3162 / 3163
页数：2
相关论文
共 50 条
  • [1] Light-patterned and recognition-directed adsorption of nanoparticles at a silicon wafer substrate
    Ryan, D
    Nagle, L
    Fitzmaurice, D
    NANO LETTERS, 2004, 4 (04) : 573 - 575
  • [2] Molecular recognition-directed solid-state self-assembly of polyhydroxy compounds with aromatic bases
    Jayaraman, A
    Balasubramanian, V
    Valiyaveettil, S
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2005, 229 : U526 - U526
  • [3] MOLECULAR-RECOGNITION-DIRECTED SELF-ASSEMBLY OF SUPRAMOLECULAR POLYMERS
    PERCEC, V
    HECK, J
    JOHANSSON, G
    TOMAZOS, D
    KAWASUMI, M
    UNGAR, G
    JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY, 1994, A31 (08): : 1031 - 1070
  • [4] Patterned surfaces via self-assembly
    Cox, JK
    Eisenberg, A
    Lennox, RB
    CURRENT OPINION IN COLLOID & INTERFACE SCIENCE, 1999, 4 (01) : 52 - 59
  • [5] Directed Self-Assembly of Nanoparticles
    Grzelczak, Marek
    Vermant, Jan
    Furst, Eric M.
    Liz-Marzan, Luis M.
    ACS NANO, 2010, 4 (07) : 3591 - 3605
  • [6] Self-Assembly of Lithographically Patterned Nanoparticles
    Cho, Jeong-Hyun
    Gracias, David H.
    NANO LETTERS, 2009, 9 (12) : 4049 - 4052
  • [7] Fabrication of chemically patterned surfaces based on template-directed self-assembly
    Lu, N
    Gleiche, M
    Zheng, JW
    Lenhert, S
    Xu, B
    Chi, LF
    Fuchs, H
    ADVANCED MATERIALS, 2002, 14 (24) : 1812 - 1815
  • [8] Directed self-assembly of silica nanoparticles into nanometer-scale patterned surfaces using spin-coating
    Xia, DY
    Biswas, A
    Li, D
    Brueck, SRJ
    ADVANCED MATERIALS, 2004, 16 (16) : 1427 - +
  • [9] Directed Orthogonal Self-Assembly of Homochiral Coordination Polymers for Heterogeneous Enantioselective Hydrogenation
    Yu, Liting
    Wang, Zheng
    Wu, Jiang
    Tu, Shujiang
    Ding, Kuiling
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (21) : 3627 - 3630
  • [10] Directed Self-Assembly of Nanoparticles for Nanomotors
    Dong, Bin
    Zhou, Tian
    Zhang, Hui
    Li, Christopher Y.
    ACS NANO, 2013, 7 (06) : 5192 - 5198
12345