Two-dimensional Structures of Isobutenyl Ether Compounds Possessing Dodecyl and Tridecyl Chains: Effects of Solvent and Tandem Claisen Rearrangement

被引：4
作者：
Kikkawa, Yoshihiro [1 ]
Omori, Kazuhiro [1 ,2 ]
Kanesato, Masatoshi [1 ]
Hiratani, Kazuhisa [1 ]
机构：
[1] Natl Inst Adv Ind Sci & Technol, Tsukuba, Ibaraki 3058562, Japan
[2] Ind Technol Ctr Tochigi Prefecture, Sano, Tochigi 3270847, Japan
来源：
CHEMISTRY LETTERS | 2012年 / 41卷 / 10期
关键词：
SCANNING-TUNNELING-MICROSCOPY; MOLECULAR NANOSTRUCTURES; SURFACES; STM; INTERFACE; CHEMISTRY;
D O I：
10.1246/cl.2012.1196
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two-dimensional (2D) structures of isobutenyl ether compounds possessing relatively short alkyl tails (carbon numbers = 12 and 13) were studied using scanning tunneling microscopy at a solid/liquid interface. Coadsorption of solvent molecules was partly dependent on the alkyl chain lengths of the isobutenyl compounds and solvents. Tandem Claisen rearrangement induced structural convergence, and the solvent effect was completely quenched.
引用
收藏
页码：1196 / 1198
页数：3
相关论文
共 24 条
  • [1] Forming nanomaterials as layered functional structures toward materials nanoarchitectonics
    Ariga, Katsuhiko
    Ji, Qingmin
    Hill, Jonathan P.
    Bando, Yoshio
    Aono, Masakazu
    [J]. NPG ASIA MATERIALS, 2012, 4 : e17 - e17
  • [2] Engineering atomic and molecular nanostructures at surfaces
    Barth, JV
    Costantini, G
    Kern, K
    [J]. NATURE, 2005, 437 (7059) : 671 - 679
  • [3] Self-assembly at the liquid/solid interface: STM reveals
    De Feyter, S
    De Schryver, FC
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (10) : 4290 - 4302
  • [4] Two-dimensional supramolecular self-assembly probed by scanning tunneling microscopy
    De Feyter, S
    De Schryver, FC
    [J]. CHEMICAL SOCIETY REVIEWS, 2003, 32 (03) : 139 - 150
  • [5] Molecular and Supramolecular Networks on Surfaces: From Two-Dimensional Crystal Engineering to Reactivity
    Elemans, Johannes A. A. W.
    Lei, Shengbin
    De Feyter, Steven
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (40) : 7298 - 7332
  • [6] Assembly of functional molecular nanostructures on surfaces
    Gomar-Nadal, Elba
    Puigmarti-Luis, Josep
    Amabilino, David B.
    [J]. CHEMICAL SOCIETY REVIEWS, 2008, 37 (03) : 490 - 504
  • [7] The tandem Claisen rearrangement in the construction of building blocks for supramolecular chemistry
    Hiratani, Kazuhisa
    Albrecht, Markus
    [J]. CHEMICAL SOCIETY REVIEWS, 2008, 37 (11) : 2413 - 2421
  • [8] Inorganic thin-film combinatorial studies for rapidly optimising functional properties
    Kafizas, Andreas
    Parkin, Ivan P.
    [J]. CHEMICAL SOCIETY REVIEWS, 2012, 41 (02) : 738 - 781
  • [9] Formation of 2D structures and their transformation by external stimuli: a scanning tunneling microscopy, study
    Kikkawa, Yoshihiro
    [J]. POLYMER JOURNAL, 2013, 45 (03) : 255 - 260
  • [10] Effects of alkyl chain length, solvent and tandem Claisen rearrangement on two-dimensional structures of noncyclic isobutenyl compounds: scanning tunnelling microscopic study
    Kikkawa, Yoshihiro
    Omori, Kazuhiro
    Takahashi, Mayuko
    Kanesato, Masatoshi
    Hiratani, Kazuhisa
    [J]. ORGANIC & BIOMOLECULAR CHEMISTRY, 2012, 10 (40) : 8087 - 8094
123