Nonisothermal crystallization of poly(ethylene-co-glycidyl methacrylate)/clay nanocomposites

被引：19
作者：
Huang, JW [1 ]
Hung, HC
Tseng, KS
Kang, CC
机构：
[1] Tainan Womans Coll Arts & Technol, Dept Styling & Cosmetol, Yung Kang 710, Taiwan
[2] Tainan Womans Coll Arts & Technol, Dept Living Sci, Yung Kang 710, Taiwan
[3] Taroko Int Co Ltd, R&D Ctr, Yung Kang 710, Taiwan
来源：
JOURNAL OF APPLIED POLYMER SCIENCE | 2006年 / 100卷 / 02期
关键词：
clay; nanocomposite; nonisothermal; crystallization; kinetics;
D O I：
10.1002/app.23199
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The nonisothermal crystallization of poly(ethylene-co-glycidyl methacrylate) (PEGMA) and PEGMA/ clay were studied by differential scanning calorimeter, at various cooling rates. Avrami model modified by Jeziorny, Ozawa mode and Liu model could successfully describe the nonisothermal crystallization process. Augis-Bennett model, Kissinger model, Takhor model, and Ziabicki model were used to evaluate the activation energy of both samples. It was found that the activation energy of PEGMA/clay nanocomposite was higher than that of neat PEGMA. Experimental results also indicated that the addition of modified clay might retard the overall nonisothermal crystallization process of PEGMA.
引用
收藏
页码：1335 / 1343
页数：9
相关论文
共 50 条
  • [41] Rheology, mechanical properties and crystallization behavior of glycidyl methacrylate grafted poly(ethylene octene) toughened poly(lactic acid) blends
    Zhao, Yan
    Zhang, Ye
    Li, Zonglin
    Pan, Hongwei
    Dong, Qinglin
    Han, Lijing
    Zhang, Huiliang
    Dong, Lisong
    KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2016, 33 (03) : 1104 - 1114
  • [42] Preparation of exfoliated clay/polymer nanocomposites via organosilane grafting and in situ ATRP of glycidyl methacrylate
    Djouani, Fatma
    Herbst, Frederic
    Chehimi, Mohamed M.
    Benzarti, Karim
    SURFACE AND INTERFACE ANALYSIS, 2010, 42 (6-7) : 1019 - 1024
  • [43] Crystallization of Poly (ethylene glycol) in Poly (methyl methacrylate) Networks
    Li, Yong
    Ma, Qiuhua
    Huang, Caiyi
    Liu, Guoqin
    MATERIALS SCIENCE-MEDZIAGOTYRA, 2013, 19 (02): : 147 - 151
  • [44] Poly(ethylene terephthalate)/Poly(ethylene glycol-co-1,3/1,4-cyclohexanedimethanol terephthalate)/Clay Nanocomposites: Morphology and Isothermal Crystallization Kinetics
    Wu, Jyh-Horng
    Yen, Ming-Shien
    Kuo, M. C.
    Wu, Chien-Pang
    Leu, Ming-Tsong
    Li, Chia-Hao
    Tsai, F. K.
    JOURNAL OF APPLIED POLYMER SCIENCE, 2013, 128 (01) : 487 - 497
  • [45] Nonisothermal crystallization behavior of poly (butylene terephthalate)-poly (ethylene terephthalate-co-isophthalate-co-sebacate) segmented copolyesters
    Zhao, YH
    Sheng, J
    Wang, YQ
    JOURNAL OF APPLIED POLYMER SCIENCE, 2003, 87 (08) : 1232 - 1238
  • [46] Effect of clay loading on flammability of poly(methyl methacrylate)/clay nanocomposites
    Pandey, Priyanka
    Dayanidhi, Anbu
    Mohanty, Smita
    Nayak, Sanjay K.
    JOURNAL OF THERMOPLASTIC COMPOSITE MATERIALS, 2013, 26 (05) : 663 - 679
  • [47] Synergetic toughening of poly(phenylene sulfide) by poly(phenylsulfone) and poly(ethylene-ran-methacrylate-ran-glycidyl methacrylate)
    Nara, Saori
    Sagawa, Hiroki
    Saito, Hiromu
    Oyama, Hideko T.
    JOURNAL OF APPLIED POLYMER SCIENCE, 2021, 138 (04)
  • [48] Synthesis and characterization of poly(glycidyl methacrylate)/Na-montmorillonite nanocomposites
    Çelik, M
    Önal, M
    JOURNAL OF APPLIED POLYMER SCIENCE, 2004, 94 (04) : 1532 - 1538
  • [49] Suspension Polymerization of Poly(methyl methacrylate)/Clay Nanocomposites
    Clarke, Nigel
    Hutchings, Lian R.
    Robinson, Ian
    Elder, Judith A.
    Collins, Stephen A.
    JOURNAL OF APPLIED POLYMER SCIENCE, 2009, 113 (02) : 1307 - 1315
  • [50] Nonisothermal crystallization behavior of melt-intercalated polyethylene-clay nanocomposites
    Yuan, Q.
    Awate, S.
    Misra, R. D. K.
    JOURNAL OF APPLIED POLYMER SCIENCE, 2006, 102 (04) : 3809 - 3818
12345