Reduced Graphene Oxide Supported Ag Nanoparticles: An Efficient Catalyst for CO2 Conversion at Ambient Conditions

被引：27
作者：
Zhang, Xiao [1 ,2 ]
Chen, Kai-Hong [1 ,2 ]
Zhou, Zhi-Hua [1 ,2 ]
He, Liang-Nian [1 ,2 ]
机构：
[1] Nankai Univ, State Key Lab, Coll Chem, Tianjin 300071, Peoples R China
[2] Nankai Univ, Inst Elementoorgan Chem, Coll Chem, Tianjin 300071, Peoples R China
来源：
CHEMCATCHEM | 2020年 / 12卷 / 19期
基金：
中国国家自然科学基金; 中国博士后科学基金;
关键词：
carboxylative cyclization; carbon dioxide; graphene oxide; heterogeneous catalyst; sliver nanoparticles; CARBON-DIOXIDE INCORPORATION; PROPARGYLIC ALCOHOLS; IONIC LIQUIDS; CARBOXYLATIVE CYCLIZATION; 2-OXAZOLIDINONES; TRANSFORMATION; AMINES; FIXATION; SYSTEM; ROUTE;
D O I：
10.1002/cctc.202000738
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A highly efficient carboxylative cyclization of propargylic alcohols with CO(2)under atmospheric pressure catalyzed by silver (0) nanoparticles decorated reduced graphene oxide (Ag-rGO) is reported. Ag-rGO was fully characterized by scanning electron microscope spectra (SEM), transmission electron microscopy (TEM), Fourier transform infrared (FT-IR) spectra, Raman spectra and X-ray photoelectron spectroscopy (XPS). Notably, Ag-rGO can be also applied to the construction of other value-added chemicals (beta-oxopropylcarbamates and 2-oxazolidinones) from CO(2)at ambient conditions. In addition, Ag-rGO is stable and reusable, which shows the potential for the practical application for CO(2)capture and utilization (CCU).
引用
收藏
页码：4825 / 4830
页数：6
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