The Effect of Injection Molding Temperature on the Morphology and Mechanical Properties of PP/PET Blends and Microfibrillar Composites

被引:48
作者
Kuzmanovic, Maja [1 ]
Delva, Laurens [1 ]
Cardon, Ludwig [1 ]
Ragaert, Kim [1 ]
机构
[1] Univ Ghent, Fac Engn & Architecture, Dept Mat Sci & Engn, Res Grp Ctr Polymer & Mat Technol, Technol Pk 915, B-9052 Ghent, Belgium
关键词
microfibrillar composites; injection molding; thermal properties; morphology; mechanical properties; POLYMER-POLYMER COMPOSITES; POLYETHYLENE TEREPHTHALATE BLENDS; SLIT-DIE EXTRUSION; REINFORCED COMPOSITES; NONISOTHERMAL CRYSTALLIZATION; ISOTACTIC POLYPROPYLENE; THERMAL-PROPERTIES; POLY(ETHYLENE-TEREPHTHALATE); COMPATIBILIZATION; COALESCENCE;
D O I
10.3390/polym8100355
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Within this research the effect of injection molding temperature on polypropylene (PP)/poly(ethylene terephthalate) (PET) blends and microfibrillar composites was investigated. Injection molding blends (IMBs) and microfibrillar composites (MFCs) of PP/PET have been prepared in a weight ratio 70/30. The samples were processed at three different injection molding temperatures (T-im) (210, 230, 280 degrees C) and subjected to extensive characterization. The observations from the fracture surfaces of MFCs showed that PET fibers can be achieved by three step processing. The results indicated that T-im has a big influence on morphology of IMBs and MFCs. With increasing the T-im, distinctive variations in particle and fiber diameters were noticed. The differences in mechanical performances were obtained by flexural and impact tests. Establishing relationships between the processing parameters, properties, and morphology of composites is of key importance for the valorization of MFC polymers.
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页数:16
相关论文
共 54 条
[1]   Fabrication of the Self-Reinforced Composites Using Co-Extrusion Technique [J].
Andrzejewski, Jacek ;
Szostak, Marek ;
Barczewski, Mateusz ;
Krasucki, Janusz ;
Sterzynski, Tomasz .
JOURNAL OF APPLIED POLYMER SCIENCE, 2014, 131 (23)
[2]   Thermal and impact study of PP/PET fibre composites compatibilized with Glycidyl Methacrylate and Maleic Anhydride [J].
Asgari, Mohammad ;
Masoomi, Mahmood .
COMPOSITES PART B-ENGINEERING, 2012, 43 (03) :1164-1170
[3]   Molecular Weight and Crystallization Temperature Effects on Poly(ethylene terephthalate) (PET) Homopolymers, an Isothermal Crystallization Analysis [J].
Baldenegro-Perez, Leonardo A. ;
Navarro-Rodriguez, Damaso ;
Medellin-Rodriguez, Francisco J. ;
Hsiao, Benjamin ;
Avila-Orta, Carlos A. ;
Sics, Igors .
POLYMERS, 2014, 6 (02) :583-600
[4]  
Bhattacharyya D., 2009, PROCESSING FABRICATI, V2, P1320
[5]   Supermolecular structure and thermal properties of poly(ethylene terephthalate)/lignin composites [J].
Canetti, Maurizio ;
Bertini, Fabio .
COMPOSITES SCIENCE AND TECHNOLOGY, 2007, 67 (15-16) :3151-3157
[6]   Reactive compatibilization of polypropylene polyethylene terephthalate blends [J].
Champagne, MF ;
Huneault, MA ;
Roux, C ;
Peyrel, W .
POLYMER ENGINEERING AND SCIENCE, 1999, 39 (06) :976-984
[7]   Compatibilization of poly(ethylene terephthalate)/polypropylene blends with maleic anhydride grafted polyethylene-octene elastomer [J].
Chiu, HT ;
Hsiao, YK .
JOURNAL OF POLYMER RESEARCH, 2006, 13 (02) :153-160
[8]  
Evstatiev O., 2005, EFFECT COMPATIBILIZA
[9]   Nanofibril reinforced composites from polymer blends [J].
Fakirov, S. ;
Bhattacharyya, D. ;
Shields, R. J. .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2008, 313 (2-8) :2-8
[10]   Contribution of coalescence to microfibril formation in polymer blends during cold drawing [J].
Fakirov, S. ;
Bhattacharyya, D. ;
Lin, R. J. T. ;
Fuchs, C. ;
Friedrich, K. .
JOURNAL OF MACROMOLECULAR SCIENCE PART B-PHYSICS, 2007, 46 (01) :183-193