Hafnocene catalyst for polyethylene and its nanocomposites with SBA-15 by in situ polymerization: Immobilization approaches, catalytic behavior and properties evaluation

被引：7

作者：

Ferreira, Ana E. ^{[1
,2
]}

Cerrada, Maria L. ^{[3
]}

Perez, Ernesto ^{[3
]}

Lorenzo, Vicente ^{[4
]}

Cramail, Henri ^{[2
]}

Lourenco, Joao P. ^{[1
,5
]}

Quijada, Raul ^{[6
,7
]}

Rosario Ribeiro, M. ^{[1
]}

机构：

[1] Univ Lisbon, Inst Super Tecn, Ctr Quim Estrutural, Av Rovisco Pais, P-1049001 Lisbon, Portugal

[2] Univ Bordeaux, Lab Chim Polymeres Organ, INP Bordeaux ENSCBP, UMR5629,CNRS, 16 Ave Pey Berland, F-33607 Pessac, France

[3] CSIC, ICTP, Juan de la Cierva 3, Madrid 28006, Spain

[4] Univ Politecn Madrid, ETSI Ind, Grp Invest POLimeros Caracterizac & Aplicac, UA ICTP CSIC, Jose Gutierrez Abascal 2, E-28006 Madrid, Spain

[5] Univ Algarve, CIQA, Fac Ciencias & Tecnol, Campus Gambelas, P-8005139 Faro, Portugal

[6] Univ Chile, Fac Ciencias Fis & Matemat, Dept Ingn Quim & Biotecnol, Casilla 2777, Santiago, Chile

[7] Millennium Nucleus Chem Proc & Catalysis CPC, Santiago, Chile

来源：

EUROPEAN POLYMER JOURNAL | 2016年 / 85卷

关键词：

Polyethylene; mesoporous SBA-15; Immobilization approaches; Nanocomposites; Crystallinity; Indentation; ETHYLENE POLYMERIZATION; OLEFIN POLYMERIZATION; MECHANICAL-PROPERTIES; GROUP-4; METALLOCENE; LIGAND STRUCTURE; INDENTATION; ZIRCONOCENE; MCM-41; MAO; PERFORMANCE;

D O I：

10.1016/j.eurpolymj.2016.10.033

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A hafnocene catalyst combined with methylaluminoxane (MAO) has been used as catalytic complex for the preparation of a set of polyethylene homopolymers by in situ polymerization under homogenous conditions and of different nanocomposites with mesoporous SBA-15 particles, the latter playing the dual role of catalyst support and nanofiller. Distinct immobilization approaches have been explored for obtainment of these nanocomposites. Moreover, catalytic features, thermal stability, melting and crystallization transitions and mechanical behavior have been evaluated for those materials. (C) 2016 Elsevier Ltd. All rights reserved.

引用

页码：298 / 312

页数：15

共 14 条

[1] Hafnocene catalyst for polyethylene and its nanocomposites with SBA-15 by in situ polymerization: Immobilization approaches, catalytic behavior and properties evaluation
Cerrada, María L. (mlcerrada@ictp.csic.es), 1600, Elsevier Ltd (85):
[2] UHMWPE/SBA-15 nanocomposites synthesized by in situ polymerization
Ferreira, Ana E.
Cerrada, Maria L.
Perez, Ernesto
Lorenzo, Vicente
Cramail, Henri
Lourenco, Joao P.
Ribeiro, M. Rosario
MICROPOROUS AND MESOPOROUS MATERIALS, 2016, 232 : 13 - 25
[3] Crystallization behavior of poly(trimethylene terephthalate)/mesoporous silica SBA-15 composites prepared by in situ polymerization
Yin, Li
Wu, Defeng
Yao, Zhen
Feng, Saihua
Zhang, Ming
Gao, Yufang
THERMOCHIMICA ACTA, 2013, 565 : 72 - 81
[4] Hybrid materials obtained by in situ polymerization based on polypropylene and mesoporous SBA-15 silica particles: Catalytic aspects, crystalline details and mechanical behavior
Barranco-Garcia, Rosa
Ferreira, Ana E.
Rosario Ribeiro, M.
Lorenzo, Vicente
Garcia-Penas, Alberto
Gomez-Elvira, Jose M.
Perez, Ernesto
Cerrada, Maria L.
POLYMER, 2018, 151 : 218 - 230
[5] Catalytic behavior and kinetic features of FeOx/SBA-15 catalyst for selective oxidation of methane by oxygen
Zhang, Qinghong
Li, Yang
An, Dongli
Wang, Ye
APPLIED CATALYSIS A-GENERAL, 2009, 356 (01) : 103 - 111
[6] Morphological modifications of Cr/SBA-15 and Cr/Al-SBA-15 ethylene polymerization catalysts: Influence on catalytic behaviour and polymer properties
Aguado, J.
Calleja, G.
Carrero, A.
Moreno, J.
MICROPOROUS AND MESOPOROUS MATERIALS, 2010, 131 (1-3) : 294 - 302
[7] Effects of mesoporous SBA-15 contents on the properties of polystyrene composites via in-situ emulsion polymerization
Chen, Zhengji
Song, Cheng
Bai, Rui
Wei, Zhibo
Zhang, Faai
JOURNAL OF POLYMER RESEARCH, 2012, 19 (03)
[8] Polypropylene Nanocomposites Attained by In Situ Polymerization Using SBA-15 Particles as Support for Metallocene Catalysts: Effect of Molecular Weight and Tacticity on Crystalline Details, Phase Transitions and Rheological Behavior
Barranco-Garcia, Rosa
Garcia-Penas, Alberto
Blazquez-Blazquez, Enrique
Ressia, Jorge A.
Quinzani, Lidia M.
Valles, Enrique M.
Gomez-Elvira, Jose M.
Perez, Ernesto
Cerrada, Maria L.
MOLECULES, 2023, 28 (11):
[9] In-situ ultrasonic synthesis of Palladium nanorods into mesoporous channel of SBA-15 and its enhanced catalytic activity for Suzuki coupling reaction
Li, Jiazhe
Bai, Xuefeng
Lv, Hongfei
MICROPOROUS AND MESOPOROUS MATERIALS, 2019, 275 : 69 - 75
[10] Preparation and characterization of Ni-Agx/SBA-15 and its catalytic properties on the hydrogenation of soybean oil
Du, Jing
Zou, Dezhi
Zhao, Yue
Chen, Jun
Jiang, Lianzhou
Liu, Tianyi
Yu, Dianyu
Li, Wenbin
Elfalleh, Walid
JOURNAL OF FOOD PROCESS ENGINEERING, 2018, 41 (08)

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