Influence of maleic anhydride grafted polypropylene on the miscibility of polypropylene/polyamide-6 blends using ATR-FTIR mapping

被引：45

作者：

Zhou, Xin ^{[1
]}

Zhang, Pudun ^{[1
]}

Jiang, Xiaoting ^{[1
]}

Rao, Guoying ^{[1
]}

机构：

[1] Beijing Univ Chem Technol, Sch Sci, Beijing 100029, Peoples R China

来源：

VIBRATIONAL SPECTROSCOPY | 2009年 / 49卷 / 01期

关键词：

ATR-FTIR; Mapping; Miscibility; Maleic anhydride grafted polypropylene; Polypropylene; Polyamide-6; MECHANICAL-PROPERTIES; MORPHOLOGY; PHASE; COMPATIBILIZATION; SPECTROMETRY; BEHAVIOR; CELLS;

D O I：

10.1016/j.vibspec.2008.04.004

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

In this work we describe an approach to study the influence of the compatibilizer, maleic anhydride grafted polypropylene (PP-g-MAH), on the miscibility of polypropylene/polyamide-6 blends (PP/PA6) using attenuated total reflectance-Fourier transform infrared (ATR-FTIR) spectroscopic mapping. In measurement, the image area for each blend was 100 mu m x 100 mu m. Different amounts of PP-g-MAH were introduced into the polymer blends, and the miscibility was characterized by the spatial distribution of PA6 in the image based on the corrected absorbance at 1640 cm(-1). It was found that small quantities of the compatibilizer Could significantly improve the miscibility of the two immiscible polymers. Furthermore, our results proved that blend with 6 parts of PP-g-MAH by weight exhibited an optimal miscibility behavior. This paper demonstrates that ATR-FTIR mapping is a direct method to visualize the miscibility of polymer blends. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：17 / 21

页数：5

共 40 条

[1] Infrared spectroscopic characterization of mineralized tissues [J].

Boskey, AL ;

Mendelsohn, R .

VIBRATIONAL SPECTROSCOPY, 2005, 38 (1-2) :107-114

[2] In situ high-throughput study of drug polymorphism under controlled temperature and humidity using FT-IR spectroscopic imaging [J].

Chan, K. L. A. ;

Kazarian, S. G. ;

Vassou, D. ;

Gionis, V. ;

Chryssikos, G. D. .

VIBRATIONAL SPECTROSCOPY, 2007, 43 (01) :221-226

[3] ATR-FTIR spectroscopic imaging with expanded field of view to study formulations and dissolution [J].

Chan, K. L. Andrew ;

Kazarian, Sergei G. .

LAB ON A CHIP, 2006, 6 (07) :864-870

[4] Applications of attenuated total reflection infrared spectroscopic imaging to pharmaceutical formulations [J].

Chan, KLA ;

Hammond, SV ;

Kazarian, SG .

ANALYTICAL CHEMISTRY, 2003, 75 (09) :2140-2146

[5] Compatibilizing effect of maleated polypropylene on the mechanical properties and morphology of injection molded polyamide 6/polypropylene/organoclay nanocomposites [J].

Chow, WS ;

Ishak, ZAM ;

Karger-Kocsis, J ;

Apostolov, AA ;

Ishiaku, US .

POLYMER, 2003, 44 (24) :7427-7440

[6] Studying skin of an Egyptian mummy by infrared microscopy [J].

Cotte, M ;

Walter, P ;

Tsoucaris, G ;

Dumas, P .

VIBRATIONAL SPECTROSCOPY, 2005, 38 (1-2) :159-167

[7]

CUPPER A, 2002, APPL SPECTROSC, V56, P1515

[8] Methods for determining the spatial distribution of oxidation in ultra-high molecular-weight polyethylene prostheses [J].

Dalborg, M. ;

Jacobson, K. ;

Jonsson, S. .

POLYMER DEGRADATION AND STABILITY, 2007, 92 (03) :437-447

[9] High-pressure CO2-enhanced polymer interdiffusion and dissolution studied with in situ ATR-FTIR spectroscopic imaging [J].

Fleming, Oliver S. ;

Chan, K. L. Andrew ;

Kazarian, Sergel G. .

POLYMER, 2006, 47 (13) :4649-4658

[10] FT-IR imaging and Raman microscopic study of poly(ethylene terephthalate) film processed with supercritical CO2 [J].

Fleming, OS ;

Chan, KLA ;

Kazarian, SG .

VIBRATIONAL SPECTROSCOPY, 2004, 35 (1-2) :3-7

← 1 2 3 4 →