Ferric porphyrin-based polymers for electrochemical oxygen reduction

被引：8
作者：
Banerjee, Subhabrata [1 ]
Nabae, Yuta [1 ]
机构：
[1] Tokyo Inst Technol, Dept Mat Sci & Engn, Meguro Ku, 21-21-S8-26 Ookayama, Tokyo 1528552, Japan
来源：
CATALYSIS TODAY | 2019年 / 332卷
关键词：
Electrocatalysis; Oxygen reduction; Metallopolymer; Fuel cell; H2O2; synthesis; Non-precious metal; HYDROGEN-PEROXIDE; CATHODE CATALYST;
D O I：
10.1016/j.cattod.2018.06.048
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Electrochemical oxygen reduction reaction (ORR) is a very important reaction for green and sustainable chemistry. Herein, we report the design and synthesis of a semi-crystalline metallopolymer consisting of ferric porphyrin-based building blocks immobilized by organic linkers (viz. various dialdehydes) through rigid imine bonds. All the materials thus obtained showed moderate to high ORR performance in rotating ring-disk electrode voltammetry with oxygen-saturated 0.5 M H2SO4 and 0.1 M KOH.
引用
收藏
页码：109 / 114
页数：6
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