An ultrasound-promoted green approach for the N-formylation of amines under solvent- and catalyst-free conditions at room temperature

被引：26

作者：

Habibi, Davood ^{[1
]}

Nasrollahzadeh, Mahmoud ^{[1
]}

机构：

[1] Bu Ali Sina Univ, Fac Chem, Dept Organ Chem, Hamadan 6517838683, Iran

来源：

COMPTES RENDUS CHIMIE | 2013年 / 16卷 / 11期

关键词：

N-Formylation; Formic acid; Amine; Ultrasound irradiation; Solvent-free; Catalyst-free; SECONDARY-AMINES; FORMIC-ACID; HETEROGENEOUS CATALYST; AEROBIC OXIDATION; CONVENIENT METHOD; HYDROGEN-STORAGE; AQUEOUS-SOLUTION; FACILE METHOD; ANILINES; FECL3-SIO2;

D O I：

10.1016/j.crci.2013.02.020

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new environmentally benign, convenient, and facile methodology for the N-formylation of amines is reported using ultrasound irradiation under solvent- and catalyst-free conditions at room temperature. Compared with conventional methods, the main advantages of the present procedure are milder, cleaner and greener conditions, shorter reaction time, higher purity and yields, simpler work-up, and lower generation of waste or pollutions. (C) 2013 Academie des sciences. Published by Elsevier Masson SAS. All rights reserved.

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页码：1008 / 1016

页数：9

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