The synthesis of bismuth sulfide, antimony sulfide, and their solid solutions from tribenzylbismuth, tribenzylantimony, and elemental sulfur

被引：0

作者：

Remington, Michael P., Jr. ^{[1
]}

Boudjouk, Philip ^{[1
]}

机构：

[1] N Dakota State Univ, Dept Chem & Biochem, Fargo, ND 58105 USA

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2016年 / 191卷 / 01期

关键词：

Chalcogenides; semiconductors; chemical synthesis; microstructure; SINGLE-SOURCE PRECURSORS; LARGE-SCALE SYNTHESIS; THIN-FILMS; PHASE-PURE; STRUCTURAL-CHARACTERIZATION; SONOCHEMICAL METHOD; TIN SULFIDE; BI2S3; DECOMPOSITION; GROWTH;

D O I：

10.1080/10426507.2015.1085043

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The condensed phase reactions of tribenzylbismuth or tribenzylantimony and elemental sulfur under mild thermal conditions (275 degrees C) produces the respective sesquisulfides in good yields and high purity. A mixture of the perbenzylated metals and elemental sulfur produces solid solutions of the general formula (BixSb1-x)(2)S-3. It has been demonstrated that it is possible to achieve synthetic control over the size and microstructure of the as produced metal sulfide particles by simply changing reaction conditions. In combination with the condensed phase pyrolysis of tris(benzylthiolato)bismuth, five different microstructures for bismuth sulfide are accessible through compounds containing the benzyl ligand.

引用

页码：4 / 8

页数：5

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