Polyhedral Metal-Imidazolate Cages: Control of Self-Assembly and Cage to Cage Transformation

被引：124
|
作者：
Zhou, Xiao-Ping
Wu, Yuan
Li, Dan [1 ]
机构：
[1] Shantou Univ, Dept Chem, Shantou 515063, Guangdong, Peoples R China
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2013年 / 135卷 / 43期
基金：
中国国家自然科学基金;
关键词：
ORGANIC FRAMEWORKS; NANOSTRUCTURES; CONSTRUCTION; RECOGNITION; MOLECULES; DESIGN; CUBES;
D O I：
10.1021/ja4092984
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A series of neutral cubic nickel(II)-imidazolate Ni8L12X4 cages were prepared by rational choices of substituents and anions with solvothermal subcomponent self-assembly technology. Both substituents and halide anions play a critical role in the formation and stabilization of cubic cages. Changing one of the factors in the reaction will switch the final structure to a Ni14L24 rhombic dodecahedral cage. The cubic cage can transform to a large rhombic dodecahedral cage in the presence of methylamine at room temperature accompanied by a color change from purple to light yellow.
引用
收藏
页码：16062 / 16065
页数：4
相关论文
共 50 条
  • [1] Solvothermal Subcomponent Self-Assembly of Cubic Metal-Imidazolate Cages and Their Coordination Polymers
    Luo, Dong
    Zhou, Xiao-Ping
    Li, Dan
    INORGANIC CHEMISTRY, 2015, 54 (22) : 10822 - 10828
  • [2] Self-Assembly of Metal Boron Imidazolate Cages
    Zhang, De-Xiang
    Zhang, Hai-Xia
    Li, Hong-Yan
    Wen, Tian
    Zhang, Jian
    CRYSTAL GROWTH & DESIGN, 2015, 15 (05) : 2433 - 2436
  • [3] Self-Assembly of an Imidazolate-Bridged FeIII/CuII Heterometallic Cage
    Reichel, Florian
    Clegg, Jack K.
    Gloe, Karsten
    Gloe, Kerstin
    Weigand, Jan J.
    Reynolds, Jason K.
    Li, Chun-Guang
    Aldrich-Wright, Janice R.
    Kepert, Cameron J.
    Lindoy, Leonard F.
    Yao, Hong-Chang
    Li, Feng
    INORGANIC CHEMISTRY, 2014, 53 (02) : 688 - 690
  • [4] Cage molecules for self-assembly
    Hohman, J. Nathan
    Claridge, Shelley A.
    Kim, Moonhee
    Weiss, Paul S.
    MATERIALS SCIENCE & ENGINEERING R-REPORTS, 2010, 70 (3-6): : 188 - 208
  • [5] Cage molecule self-assembly
    Weiss, Paul
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 254
  • [6] Cage molecule self-assembly
    Weiss, Paul
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 253
  • [7] Anion control in the self-assembly of a cage coordination complex
    Vilar, R.
    Mingos, D.M.P.
    White, A.J.P.
    Williams, D.J.
    Angewandte Chemie (International Edition in English), 1998, 37 (09): : 1258 - 1261
  • [8] Anion control in the self-assembly of a cage coordination complex
    Vilar, R
    Mingos, DMP
    White, AJP
    Williams, DJ
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1998, 37 (09) : 1258 - 1261
  • [9] Simulations of clathrin self-assembly into polyhedral cages
    den Otter, W. K.
    Briels, W. J.
    EUROPEAN BIOPHYSICS JOURNAL WITH BIOPHYSICS LETTERS, 2011, 40 : 104 - 104
  • [10] Multicomponent Self-Assembly of PdII/PtII Interlocked Molecular Cages: Cage-to-Cage Conversion and Self-Sorting in Aqueous Medium
    Kumar, Atul
    Mukherjee, Partha Sarathi
    CHEMISTRY-A EUROPEAN JOURNAL, 2020, 26 (21) : 4842 - 4849
12345