The influence of torrefaction on pyrolysed biomass: The relationship of bio-oil composition with the torrefaction severity

被引：14

作者：

He, Zhen ^{[1
]}

Zhang, Fan ^{[1
]}

Tu, Ren ^{[1
]}

Jia, Zhiwen ^{[1
]}

Cheng, Shuchao ^{[1
]}

Sun, Yan ^{[1
]}

Wu, Yujian ^{[1
]}

Shen, Xiaowen ^{[1
]}

Jiang, Enchen ^{[1
]}

Xu, Xiwei ^{[1
]}

机构：

[1] South China Agr Univ, Coll Mat & Energy, Key Lab Biobased Mat & Energy, Minist Educ, 483 Wushan Rd, Guangzhou 510642, Peoples R China

来源：

BIORESOURCE TECHNOLOGY | 2020年 / 314卷

关键词：

Torrefaction; Carbon element index (CEI); Pyrolysis; Phenols; CELLULOSE; PHENOL; PRETREATMENT; DRY;

D O I：

10.1016/j.biortech.2020.123780

中图分类号：

S2 [农业工程];

学科分类号：

0828 ;

摘要：

In this study, three types of biomass were torrefied at different times (0.5, 1, 1.5 h) and temperature (200, 240, 280, 320 degrees C), which were further pyrolyzed at 550 degrees C after torrefaction. CEI (carbon element index), which was established based on the carbon content of the torrefied biomass, was chosen as an indicator for reflecting torrefaction severity. The results showed that there was a curvilinear relationship between CEI and the physicochemical characteristics, energy recovery of torrefied biomass, which obtained an average goodness of fit was higher than 0.93. Moreover, the goodness of fit between CEI and pyrolysis carbon and bio-oil yield was higher than 0.95 and 0.91, respectively. Especially, the bio-oil composition and CEI were fitted by a quadratic function (y = a + bx + cx(2)). Based on the function, the yield of phenols could be predicted based on the CEI value, which would benefit for the preparation of higher quality bio-oil directionally.

引用

页数：13

共 42 条

[31] Synthetic indicator on the severity of torrefaction of oil palm biomass residues through mass loss measurement [J].

Sabil, Khalik M. ;

Aziz, Muafah A. ;

Lal, Bhajan ;

Uemura, Yoshimitsu .

APPLIED ENERGY, 2013, 111 :821-826

[32] Industrial catalytic processes - phenol production [J].

Schmidt, RJ .

APPLIED CATALYSIS A-GENERAL, 2005, 280 (01) :89-103

[33] The mechanism of wet/dry torrefaction pretreatment on the pyrolysis performance of tobacco stalk [J].

Sun, Yan ;

He, Zhen ;

Tu, Ren ;

Wu, Yu-jian ;

Jiang, En-chen ;

Xu, Xi-wei .

BIORESOURCE TECHNOLOGY, 2019, 286

[34] Pyrolysis behaviors of four O-acetyl-preserved hemicelluloses isolated from hardwoods and softwoods [J].

Wang, Shurong ;

Ru, Bin ;

Lin, Haizhou ;

Sun, Wuxing .

FUEL, 2015, 150 :243-251

[35] Catalytic pyrolysis of larch sawdust for phenol-rich bio-oil using different catalysts [J].

Wang, Wenliang ;

Li, Xinping ;

Ye, Dan ;

Cai, LiPing ;

Sheldon, Q. .

RENEWABLE ENERGY, 2018, 121 :146-152

[36] Comparative study of wet and dry torrefaction of corn stalk and the effect on biomass pyrolysis polygeneration [J].

Wang, Xianhua ;

Wu, Jing ;

Chen, Yingquan ;

Pattiya, Adisak ;

Yang, Haiping ;

Chen, Hanping .

BIORESOURCE TECHNOLOGY, 2018, 258 :88-97

[37] Assessing the chemical composition of heavy components in bio-oils from the pyrolysis of cellulose, hemicellulose and lignin at slow and fast heating rates [J].

Xiong, Zhe ;

Guo, Junhao ;

Chaiwat, Weerawut ;

Deng, Wei ;

Hu, Xun ;

Han, Hengda ;

Chen, Yuanjing ;

Xu, Kai ;

Su, Sheng ;

Hu, Song ;

Wang, Yi ;

Xiang, Jun .

FUEL PROCESSING TECHNOLOGY, 2020, 199

[38] Influence of biomass pretreatment on upgrading of bio-oil: Comparison of dry and hydrothermal torrefaction [J].

Xu Xiwei ;

Tu Ren ;

Sun Yan ;

Li Zhiyu ;

Jiang Enchen .

BIORESOURCE TECHNOLOGY, 2018, 262 :261-270

[39] Dry and steam reforming of biomass pyrolysis gas for rich hydrogen gas [J].

Xu, Xiwei ;

Jiang, Enchen ;

Wang, Mingfeng ;

Xu, Youjie .

BIOMASS & BIOENERGY, 2015, 78 :6-16

[40] Fast pyrolysis of biomass catalyzed by magnetic solid base catalyst in a hydrogen atmosphere for selective production of phenol [J].

Zhang, Zhen-xi ;

Li, Kai ;

Ma, Shan-wei ;

Cui, Min-shu ;

Lu, Qiang ;

Yang, Yong-ping .

INDUSTRIAL CROPS AND PRODUCTS, 2019, 137 (495-500) :495-500

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