The influence of torrefaction on pyrolysed biomass: The relationship of bio-oil composition with the torrefaction severity

被引:14
作者
He, Zhen [1 ]
Zhang, Fan [1 ]
Tu, Ren [1 ]
Jia, Zhiwen [1 ]
Cheng, Shuchao [1 ]
Sun, Yan [1 ]
Wu, Yujian [1 ]
Shen, Xiaowen [1 ]
Jiang, Enchen [1 ]
Xu, Xiwei [1 ]
机构
[1] South China Agr Univ, Coll Mat & Energy, Key Lab Biobased Mat & Energy, Minist Educ, 483 Wushan Rd, Guangzhou 510642, Peoples R China
关键词
Torrefaction; Carbon element index (CEI); Pyrolysis; Phenols; CELLULOSE; PHENOL; PRETREATMENT; DRY;
D O I
10.1016/j.biortech.2020.123780
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
In this study, three types of biomass were torrefied at different times (0.5, 1, 1.5 h) and temperature (200, 240, 280, 320 degrees C), which were further pyrolyzed at 550 degrees C after torrefaction. CEI (carbon element index), which was established based on the carbon content of the torrefied biomass, was chosen as an indicator for reflecting torrefaction severity. The results showed that there was a curvilinear relationship between CEI and the physicochemical characteristics, energy recovery of torrefied biomass, which obtained an average goodness of fit was higher than 0.93. Moreover, the goodness of fit between CEI and pyrolysis carbon and bio-oil yield was higher than 0.95 and 0.91, respectively. Especially, the bio-oil composition and CEI were fitted by a quadratic function (y = a + bx + cx(2)). Based on the function, the yield of phenols could be predicted based on the CEI value, which would benefit for the preparation of higher quality bio-oil directionally.
引用
收藏
页数:13
相关论文
共 42 条
[1]   Production of monomeric phenols by thermochemical conversion of biomass: a review [J].
Amen-Chen, C ;
Pakdel, H ;
Roy, C .
BIORESOURCE TECHNOLOGY, 2001, 79 (03) :277-299
[2]   Mathematical modeling the relations of pyrolytic products from lignocellulosic materials [J].
Arin, G ;
Demirbas, A .
ENERGY SOURCES, 2004, 26 (11) :1023-1032
[3]   Investigation of improving the yields and qualities of pyrolysis products with combination rod-milled and torrefaction pretreatment [J].
Bai, Xiaopeng ;
Wang, Guanghui ;
Zhu, Zheng ;
Cai, Chen ;
Wang, Zhiqin ;
Wang, Decheng .
RENEWABLE ENERGY, 2020, 151 :446-453
[4]   Preparation of furfural by catalytic pyrolysis of cellulose based on nano Na/Fe-solid acid [J].
Bai, Xiaowei ;
Li, Jian ;
Jia, Chenxi ;
Shao, Jingai ;
Yang, Qing ;
Chen, Yingquan ;
Yang, Haiping ;
Wang, Xianhua ;
Chen, Hanping .
FUEL, 2019, 258
[5]   Biomass torrefaction: An overview on process parameters, economic and environmental aspects and recent advancements [J].
Cahyanti, Margareta Novian ;
Doddapaneni, Tharaka Rama Krishna C. ;
Kikas, Timo .
BIORESOURCE TECHNOLOGY, 2020, 301
[6]   Upgrading of bio-oil via solar pyrolysis of the biomass pretreated with aqueous phase bio-oil washing, solar drying, and solar torrefaction [J].
Chen, Dengyu ;
Cen, Kehui ;
Cao, Xiaobing ;
Zhang, Jie ;
Chen, Fan ;
Zhou, Jianbin .
BIORESOURCE TECHNOLOGY, 2020, 305
[7]   Bamboo wastes catalytic pyrolysis with N-doped biochar catalyst for phenols products [J].
Chen, Wei ;
Fang, Yang ;
Li, Kaixu ;
Chen, Zhiqun ;
Xia, Mingwei ;
Gong, Meng ;
Chen, Yingquan ;
Yang, Haiping ;
Tu, Xin ;
Chen, Hanping .
APPLIED ENERGY, 2020, 260
[8]   Torrefaction, pyrolysis and two-stage thermodegradation of hemicellulose, cellulose and lignin [J].
Chen, Wei-Hsin ;
Wang, Chao-Wen ;
Ong, Hwai Chyuan ;
Show, Pau Loke ;
Hsieh, Tzu-Hsien .
FUEL, 2019, 258
[9]   Torrefaction operation and optimization of microalga residue for energy densification and utilization [J].
Chen, Wei-Hsin ;
Huang, Ming-Yueh ;
Chang, Jo-Shu ;
Chen, Chun-Yen .
APPLIED ENERGY, 2015, 154 :622-630
[10]   Catalytic fast pyrolysis of cellulose to produce furan compounds with SAPO is type catalysts [J].
Chen, Xu ;
Chen, Yingquan ;
Chen, Zhen ;
Zhu, Danchen ;
Yan, Haiping ;
Liu, Peng ;
Li, Tao ;
Chen, Hanping .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2018, 129 :53-60