Macrocyclic regioregular poly(3-hexylthiophene): from controlled synthesis to nanotubular assemblies

被引：15

作者：

Coulembier, Olivier ^{[1
]}

Deshayes, Gaelle ^{[1
]}

Surin, Mathieu ^{[2
]}

De Winter, Julien ^{[3
]}

Boon, Florian ^{[1
,2
]}

Delcourt, Cecile ^{[2
]}

Leclere, Philippe ^{[2
]}

Lazzaroni, Roberto ^{[2
]}

Gerbaux, Pascal ^{[3
]}

Dubois, Philippe ^{[1
]}

机构：

[1] Univ Mons, Lab Polymer & Composite Mat, Ctr Innovat & Res Mat & Polymers CIRMAP, B-7000 Mons, Belgium

[2] Univ Mons, Lab Chem Novel Mat, Ctr Innovat & Res Mat & Polymers CIRMAP, B-7000 Mons, Belgium

[3] Univ Mons, Mass Spectrometry Grp, Interdisciplinary Ctr Mass Spectrometry CISMa, B-7000 Mons, Belgium

来源：

POLYMER CHEMISTRY | 2013年 / 4卷 / 02期

关键词：

MICROSCOPIC MORPHOLOGY; HIGH CRYSTALLINITY; TRANSPORT; POLY(3-ALKYLTHIOPHENES); CHEMISTRY;

D O I：

10.1039/c2py20647a

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

An easy and quantitative cyclization procedure based on an intramolecular imperfect aldol reaction from a pre-generated regioregular poly(3-hexylthiophene) is developed. As an illustration of the versatility of this procedure, the synthesis of a representative macrocyclic poly(3-hexylthiophene) with a diameter of 5 nm is presented.

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收藏

页码：237 / 241

页数：5

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