Heterogenized Catalysts Containing Cobalt-Rhodium Heterobimetallic Nanoparticles for Olefin Hydroformylation

被引：17

作者：

Kim, Jee Young ^{[1
]}

Park, Ji Hoon ^{[2
,3
]}

Jung, Ok-Sang ^{[1
]}

Chung, Young Keun ^{[2
,3
]}

Park, Kang Hyun ^{[1
]}

机构：

[1] Pusan Natl Univ, Dept Chem, Pusan 609735, South Korea

[2] Seoul Natl Univ, Intelligent Text Syst Res Ctr, Seoul 151747, South Korea

[3] Seoul Natl Univ, Dept Chem, Coll Nat Sci, Seoul 151747, South Korea

来源：

CATALYSIS LETTERS | 2009年 / 128卷 / 3-4期

关键词：

Hydroformylation; Nanoparticle; Catalyst; Heterobimetallic; Heterogeneous catalyst; SINGLE-STEP; HYDROGENATION; ALKYNES;

D O I：

10.1007/s10562-008-9776-y

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This paper focuses on the catalysis of the hydroformylation of aliphatic olefins and aromatic olefins using the multi-faceted cobalt-rhodium heterobimetallic nanoparticle (Co2Rh2). The Co2Rh2 nanocatalyst retained its catalytic activity, allowing for 5 cycles through the reaction.

引用

页码：483 / 486

页数：4

共 29 条

[1]

Bcnnemann H., 2001, EUR J INORG CHEM, P2455

[2]

Breit B., 2001, SYNTHESIS, V1, P1

[3] Rh(0) nanoparticles as catalyst precursors for the solventless hydroformylation of olefins [J].