Aggregation-Induced Emission for Visualization in Materials Science

被引:53
作者
Li, Kaitao [1 ]
Lin, Yanjun [1 ]
Lu, Chao [1 ]
机构
[1] Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, POB 79, Beijing 100029, Peoples R China
基金
中国国家自然科学基金;
关键词
aggregation-induced emission; fluorescent imaging; morphological evolution; structural changes; visualization; METAL-ORGANIC FRAMEWORKS; CIRCULARLY-POLARIZED LUMINESCENCE; BETA-GALACTOSIDASE ACTIVITY; GLASS-TRANSITION; FLUORESCENCE VISUALIZATION; TRIGGERED-FLUORESCENCE; DRAMATIC DIFFERENCES; MECHANICAL DAMAGE; CLICK SYNTHESIS; POLYMER;
D O I
10.1002/asia.201801760
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Fluorescent imaging techniques have attracted much attention as a powerful tool to realize the visualization of structural and morphological evolution of various materials. However, the traditional fluorescent dyes usually suffered from aggregation-caused quenching, which severely limits the visualization results. In contrast, aggregation-induced emission (AIE) molecules with high quantum yields in the condensed state showed great opportunities for imaging techniques. In this feature article, recent progresses in visualization with AIE molecules are discussed. Assembly processes including crystallization, gelation process, and dissipative assembly have been observed. To better study information obtained regarding the processes, visualization during reactions, phase transitions, and molecular motions are successfully presented. Based on these successes, AIE molecules were further applied for phase recognition, macro-dispersion evaluation, and damage detection. Finally, we also present the outlook and perspectives, in our opinion, for the development of visualization by AIE molecules.
引用
收藏
页码:715 / 729
页数:15
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