Transport Properties of PbO-P2O5-ZnO-Li2O Glass System

被引：1

作者：

Lakshmikantha, R. ^{[1
]}

Rajaramakrishna, R. ^{[3
]}

Ayachit, N. H. ^{[2
]}

Anavekar, R. V. ^{[3
]}

机构：

[1] South Nijalingappa Coll, Dept Phys, KLE Soc, Bangalore 560010, Karnataka, India

[2] BVB Coll Engn & Technol, Dept Phys, Hubli 580031, India

[3] Bangalore Univ, Dept Phys, Bangalore 560056, Karnataka, India

来源：

SOLID STATE PHYSICS, PTS 1 AND 2 | 2012年 / 1447卷

关键词：

Phosphate glass; melt quenching; dc and ac conductivity; CONDUCTIVITY; IONS;

D O I：

10.1063/1.4710122

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

The electrical conductivity of Li+ ion conducting lead zinc phosphate glasses have been carried out both as a function of temperature and frequency in the temperature range 458-510K and over frequencies 40 Hz to 10 MHz. The dc conductivities show Arrhenius behavior and show compositional dependence. The sigma decreases with increase in Li2O content. The ac conductivity behavior has been analyzed using Almond-West power law using a single exponent. The exponent 's' obtained from the power law fits is found to have values ranging from 0.74 - 0.80 in these glasses and shows moderate temperature dependence, which is attributed to high degree of modification in the glass network.

引用

页码：551 / +

页数：2

共 7 条

[1] TEMPERATURE-DEPENDENCE OF THE AC CONDUCTIVITY OF NA BETA-ALUMINA
ALMOND, DP
WEST, AR
GRANT, RJ
[J]. SOLID STATE COMMUNICATIONS, 1982, 44 (08) : 1277 - 1280
[2] Mobile ions in amorphous solids
Angell, C.A.
[J]. Annual Review of Physical Chemistry, 1992, 43 (01) : 693 - 717
[3] Mixed electronic-ionic conductivity in the glasses of the Li2O-V2O5-P2O5 system
Jozwiak, P
Garbarczyk, JE
[J]. SOLID STATE IONICS, 2005, 176 (25-28) : 2163 - 2166
[4] Effects of thermal history on mechanical properties of (PbO)x(ZnO)(0.6-x)(P2O5)0.4 glasses using Brillouin scattering
Le Saoût, G
Vaills, Y
Luspin, Y
[J]. SOLID STATE COMMUNICATIONS, 2002, 123 (1-2) : 49 - 54
[5] Fluorescence spectroscopy of Sm3+ ions in P2O5-PbO-Nb2O5 glasses
Praveena, R.
Venkatramu, V.
Babu, P.
Jayasankar, C. K.
[J]. PHYSICA B-CONDENSED MATTER, 2008, 403 (19-20) : 3527 - 3534
[6] TICK PA, 1984, PHYS CHEM GLASSES, V25, P149
[7] Crystallization kinetics of a low melting PbO-ZnO-P2O5 glass
Yung, SW
Shih, PY
Chin, TS
[J]. MATERIALS CHEMISTRY AND PHYSICS, 1998, 57 (02) : 111 - 116

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