Trityl Chloride (TrCI): Efficient and Homogeneous Organocatalyst for the Solvent-Free Synthesis of 14-Aryl-14H-dibenzo[a,j]xanthenes by in situ Formation of Carbocationic System

被引：14

作者：

Zare, Abdolkarim ^{[1
]}

Merajoddin, Maria ^{[1
]}

Abi, Fereshteh ^{[1
]}

Moosavi-Zare, Ahmad Reza ^{[2
]}

Mokhlesi, Mohammad ^{[2
]}

Zolfigol, Mohammad Ali ^{[2
]}

Asgari, Zhila ^{[2
]}

Khakyzadeh, Vahid ^{[2
]}

Hasaninejad, Alireza ^{[3
]}

Khalafi-Nezhad, Ali ^{[4
]}

Parhami, Abolfath ^{[1
]}

机构：

[1] Payame Noor Univ, Dept Chem, Tehran, Iran

[2] Bu Ali Sina Univ, Fac Chem, Hamadan 6517838683, Iran

[3] Persian Gulf Univ, Fac Sci, Dept Chem, Bushehr 75169, Iran

[4] Shiraz Univ, Coll Sci, Dept Chem, Shiraz 71454, Iran

来源：

JOURNAL OF THE CHINESE CHEMICAL SOCIETY | 2012年 / 59卷 / 07期

关键词：

Trityl chloride (triphenylmethyl chloride; TrCl; Ph3CCl); Trityl carbocation; Organocatalyst; 14-Aryl-14H-dibenzo[a; j]xanthenes; beta-Naphthol; Solvent-free; ONE-POT SYNTHESIS; ROOM-TEMPERATURE; ORGANIC CATALYST; NEUTRAL MEDIA; SULFAMIC ACID; DERIVATIVES; 14-ARYL;

D O I：

10.1002/jccs.201100719

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Trityl chloride (triphenylmethyl chloride, TrCl, Ph3CCl) is utilized as an efficient and homogeneous organocatalyst for the synthesis of 14-aryl-14H-dibenzo[a,j]xanthenes from beta-naphthol and arylaldehydes under solvent-free conditions. Moreover, a plausible mechanism is suggested based on the literature and on in situ formation of trityl carbocation with inherent instability during the reaction.

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收藏

页码：860 / 865

页数：6

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