Preparation of lead oxoalkoxides from lead oxide

被引：7
|
作者：
Merkle, R [1 ]
Bertagnolli, H [1 ]
机构：
[1] Univ Stuttgart, Inst Phys Chem, D-70550 Stuttgart, Germany
来源：
POLYHEDRON | 1999年 / 18卷 / 07期
关键词：
lead oxoalkoxides; Pb6O4(OR)(4) clusters; lead oxide; IR and Raman spectroscopy; sol-gel process;
D O I：
10.1016/S0277-5387(98)00399-4
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Lead all;oxides of the types Pb4O(OR)(6) and Pb6O4(OR)(4) were prepared from PbO and the corresponding alcohols in good yields. Alkoxide exchange reactions extend the number of compounds accessible by this synthesis route. This synthesis avoids the preparation of educts like Pb[N(SiMe3)] which were used in earlier work. Due to their high solubility in alcohols, lead oxoalkoxides can provide valuable educts for the sol-gel preparation of lead containing ceramics. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：1089 / 1093
页数：5
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