Uranyl ion adsorption studies on synthesized phosphoryl functionalised MWCNTs: a mechanistic approach

被引：14

作者：

Guo, Xue ^{[1
,2
]}

Feng, Yurun ^{[1
,2
]}

Ma, Li ^{[1
,2
]}

Yu, Jincheng ^{[4
]}

Jing, Jie ^{[1
,2
]}

Gao, Dezhi ^{[1
,2
]}

Khan, Adil Saleem ^{[1
,2
]}

Gong, Hongyu ^{[1
,2
]}

Zhang, Yujun ^{[1
,2
,3
]}

机构：

[1] Shandong Univ, Minist Educ, Key Lab Liquid Solid Struct Evolut & Proc Mat, Jinan 250061, Shandong, Peoples R China

[2] Shandong Univ, Key Lab Special Funct Aggregated Mat, Minist Educ, Jinan 250061, Shandong, Peoples R China

[3] Laiwu Adv Ceram Technol Co Ltd, Laiwu 271114, Peoples R China

[4] Univ Manchester, Sch Mat, Manchester M13 9PL, Lancs, England

来源：

JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY | 2018年 / 316卷 / 01期

基金：

中国国家自然科学基金;

关键词：

MWCNTs; Uranium; Adsorption; Phosphoryl; MULTIWALLED CARBON NANOTUBES; AQUEOUS-SOLUTION; ACTIVATED CARBON; METAL-IONS; URANIUM VI; REMOVAL; SORPTION; MODELS; U(VI); PRECIPITATION;

D O I：

10.1007/s10967-018-5761-0

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A novel and efficient sorbent: phosphoryl multiwalled carbon nanotubes (PS-MWCNTs) were synthesized by modifying MWCNTs with phosphoryl functional groups. PS-MWCNTs possessed excellent uranium adsorption capacity (194.17 mg g(-1)) with a wide range of pH values (> 2) and short adsorption equilibrium time (10 min). The isotherm models revealed that the U(VI) adsorption mechanism of PS-MWCNTs mainly belonged to chemical adsorption. Furthermore, the XPS analysis showed that the main forces between uranium ions and PS-MWCNTs were attributed to the phosphoryl functional groups.

引用

页码：397 / 409

页数：13

共 29 条

[1] Preparation of a novel electrospun polyvinyl alcohol/titanium oxide nanofiber adsorbent modified with mercapto groups for uranium(VI) and thorium(IV) removal from aqueous solution [J].

Abbasizadeh, Saeed ;

Keshtkar, Ali Reza ;

Mousavian, Mohammad Ali .

CHEMICAL ENGINEERING JOURNAL, 2013, 220 :161-171

[2] Performance of MWCNTs and a low-cost adsorbent for Chromium(VI) ion removal [J].

Ahmadpour A. ;

Eftekhari N. ;

Ayati A. .

Journal of Nanostructure in Chemistry, 2014, 4 (4) :171-178

[3] Uranium extraction from aqueous solution using dried and pyrolyzed tea and coffee wastes [J].

Aly, Zaynab ;

Luca, Vittorio .

JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2013, 295 (02) :889-900

[4] Improved performance of a biomaterial-based cation exchanger for the adsorption of uranium(VI) from water and nuclear industry wastewater [J].

Anirudhan, T. S. ;

Radhakrishnan, P. G. .

JOURNAL OF ENVIRONMENTAL RADIOACTIVITY, 2009, 100 (03) :250-257

[5] Adsorption and transport of uranium(VI) in subsurface media [J].

Barnett, MO ;

Jardine, PM ;

Brooks, SC ;

Selim, HM .

SOIL SCIENCE SOCIETY OF AMERICA JOURNAL, 2000, 64 (03) :908-917

[6] Applicability of the various adsorption models of three dyes adsorption onto activated carbon prepared waste apricot [J].

Basar, Canan Akmil .

JOURNAL OF HAZARDOUS MATERIALS, 2006, 135 (1-3) :232-241

[7] Uranous sulfate precipitation as a novel hydrometallurgical process for uranium purification [J].

Burns, Alexander D. ;

Abbasi, Parisa ;

Dreisinger, David B. .

HYDROMETALLURGY, 2016, 163 :49-54

[8] Adsorption of UO22+ from aqueous solution onto copolymers of styrene and maleic anhydride [J].

Duan Guojian ;

Liu Tonghuan ;

Wu Wangsuo ;

Yang Ying .

JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2013, 295 (03) :2193-2201

[9]

Ebbesen ThomasW., 1997, CARBON NANOTUBES PRE

[10] Uranium (VI) sorption by multiwalled carbon nanotubes from aqueous solution [J].

Fasfous, Ismail I. ;

Dawoud, Jamal N. .

APPLIED SURFACE SCIENCE, 2012, 259 :433-440

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