Photoluminescent properties and Judd-Ofelt analysis of novel Na0.5Sr0.25NbO3: Eu3+ red phosphor with high quantum efficiency

被引:24
作者
Shi, Yongsheng [1 ]
Quan, Bo [2 ]
Ning, Qingju [2 ]
Cao, Shuyao [2 ]
Shi, Jingjun [1 ]
Dong, Chen [1 ]
机构
[1] Shaanxi Univ Sci & Technol, Coll Elect & Informat Engn, Xian 710021, Shaanxi, Peoples R China
[2] Shaanxi Univ Sci & Technol, Sch Mat Sci & Engn, Xian 710021, Shaanxi, Peoples R China
基金
对外科技合作项目(国际科技项目);
关键词
Molten salt synthesis method; Phosphor; Eu3+; Judd-Ofelt theory; Photoluminescence; ENERGY-TRANSFER; EMITTING PHOSPHORS; NEAR-ULTRAVIOLET; LUMINESCENCE; EMISSION; NASR2NB5O15; ENHANCEMENT; INTENSITIES; PARTICLES; WLEDS;
D O I
10.1016/j.materresbull.2018.01.044
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We report on a novel NaooSr(0.25)NbO(3): Eu3+ phosphor fabricated by a molten salt synthesis method with the potential application in white light-emitting diodes (WLEDs) as a red phosphor. The crystal structure, morphology, emission/excitation spectra, as well as decay curves were characterized with X-ray diffraction, Scanning Electron Microscope and photoluminescence spectrometer, respectively. Concentration quenching occurred when the concentration of Eu3+ was beyond 5 mol% due to the dipole-dipole interaction by non-radiative energy transfer. Besides, the effect of the crystal field surrounding the Eu3+ ions on the luminescent performance under 396 nm and 466 nm excitions has been investigated by the Judd-Ofelt theory. The result indicated that the quantum efficiency of the phosphor was 62.65% excited by 466 nm, which was superior to 41.43% excited by 396 mn. The optimal sample's CIE coordinates were (0.6471, 0.3504) with the color purity of 97%, showing a potential application in (WLEDs) illumination field.
引用
收藏
页码:363 / 370
页数:8
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