In situ X-ray Photoemission Spectroscopy Analysis of Aromatic Polyester Surface Treated with Argon Plasma

被引:0
|
作者
Narushima, Kazuo [1 ]
Okamoto, Nanami [2 ]
机构
[1] Ube Natl Coll Technol, Dept Elect Engn, Ube, Yamaguchi 7558555, Japan
[2] Shizuoka Univ, Fac Engn, Dept Mat Sci & Chem Engn, Hamamatsu, Shizuoka 4328561, Japan
关键词
OXYGEN; XPS; FLUOROPOLYMERS; DEGRADATION; IMPROVEMENT; POLYMERS; FILMS; PTFE; ESCA; PET;
D O I
10.7567/JJAP.52.106201
中图分类号
O59 [应用物理学];
学科分类号
摘要
Effects of surface modification treatment by argon plasma processing of two types of aromatic polyester, poly(ethylene terephthalate) (PET) and poly(oxybenzonate-co-oxynaphthoate) (POCO), were investigated. This paper presents a description of our experiment and a discussion of the surface modification mechanism, which uses a simple and inexpensive procedure to conduct analysis without breaking vacuum after plasma processing. In situ analysis of the chemical composition of a polymer surface was attempted without exposing the sample to air after argon plasma processing. In particular, the respective actions of each active species were investigated for electrons and ions in argon plasma. Electrons and ions in argon plasma break some polymer bonds. Specifically, ester groups are broken and oxygen atoms are kicked out in PET and POCO. No oxygen functional group is formed after argon plasma processing, but such groups are formed if the sample is exposed to air. (C) 2013 The Japan Society of Applied Physics
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页数:7
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