NMR Studies of Molten Salt and Room Temperature Ionic Liquids

被引：20

作者：

Rollet, Anne-Laure ^{[1
]}

Bessada, Catherine ^{[2
]}

机构：

[1] Univ Paris 06, CNRS, PHENIX, Paris, France

[2] CNRS, CEMHTI, F-45071 Orleans, France

来源：

ANNUAL REPORTS ON NMR SPECTROSCOPY, VOL 78 | 2013年 / 78卷

关键词：

Chemical shift; Pulsed field gradient NMR; NOE; Relaxometry; Liquid structure; Self-diffusion; NUCLEAR-MAGNETIC-RESONANCE; SOLID-STATE NMR; MOLECULAR REORIENTATIONAL DYNAMICS; SELF-DIFFUSION COEFFICIENTS; FIELD GRADIENT NMR; TRANSPORT-PROPERTIES; RARE-EARTH; PHYSICOCHEMICAL PROPERTIES; CHEMICAL-SHIFT; SPIN-ECHO;

D O I：

10.1016/B978-0-12-404716-7.00004-3

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

This chapter presents the nuclear magnetic resonance (NMR) developments and studies on the high temperature inorganic molten salts and on room temperature ionic liquids. It is focused on the liquid structure investigated, thanks to the chemical shifts analysis and to magnetization transfer experiments. It deals also with the dynamics at the local scale investigated using relaxometry and at the long range using pulsed field gradient NMR.

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收藏

页码：149 / 207

页数：59

相关论文

共 287 条

[1] Application of hole theory to the viscosity of ionic and molecular liquids [J].

Abbott, AP .

CHEMPHYSCHEM, 2004, 5 (08) :1242-1246

[2] Measuring Molecular Dynamics and Activation Energies for Quaternary Acyclic Ammonium and Cyclic Pyrrolidinium Ionic Liquids Using 14N NMR Spectroscopy [J].

Alam, Todd M. ;

Dreyer, Daniel R. ;

Bielwaski, Christopher W. ;

Ruoff, Rodney S. .

JOURNAL OF PHYSICAL CHEMISTRY A, 2011, 115 (17) :4307-4316

[3] A comparative study on the reactivity of electrogenerated bromine with cyclohexene in acetonitrile and the room temperature ionic liquid, 1-butyl-3-methylimidazolium bis[(trifluoromethyl)sulfonyl]imide [J].

Allen, GD ;

Buzzeo, MC ;

Davies, LG ;

Villagrán, C ;

Hardacre, C ;

Compton, RG .

JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (41) :16322-16327

[4] Characterization of Molecular Systems and Monitoring of Chemical Reactions in Ionic Liquids by Nuclear Magnetic Resonance Spectroscopy [J].

Ananikov, Valentine P. .

CHEMICAL REVIEWS, 2011, 111 (02) :418-454

[5]

Anil Kumar PG, 1907, INORG CHIM ACTA, V2006, P359

[6] Transport properties in ionic liquids and ionic liquid mixtures: The challenges of NMR pulsed field gradient diffusion measurements [J].

Annat, Gary ;

MacFarlane, Douglas R. ;

Forsyth, Maria .

JOURNAL OF PHYSICAL CHEMISTRY B, 2007, 111 (30) :9018-9024

[7] Transport Properties Investigation of Aqueous Protic Ionic Liquid Solutions through Conductivity, Viscosity, and NMR Self-Diffusion Measurements [J].

Anouti, Meriem ;

Jacquemin, Johan ;

Porion, Patrice .

JOURNAL OF PHYSICAL CHEMISTRY B, 2012, 116 (14) :4228-4238

[8] Transport properties in two pyrrolidinium-based protic ionic liquids as determined by conductivity, viscosity and NMR self-diffusion measurements [J].

Anouti, Meriern ;

Porion, Patrice ;

Brigouleix, Catherine ;

Galiano, Herve ;

Lernordant, Daniel .

FLUID PHASE EQUILIBRIA, 2010, 299 (02) :229-237

[9] 13C NMR relaxation rates in the ionic liquid 1-methyl-3-nonylimidazolium hexafluorophosphate [J].

Antony, JH ;

Dölle, A ;

Mertens, D ;

Wasserscheid, P ;

Carper, WR ;

Wahlbeck, PG .

JOURNAL OF PHYSICAL CHEMISTRY A, 2005, 109 (30) :6676-6682

[10] Molecular reorientational dynamics of the neat ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate by measurement of 13C nuclear magnetic relaxation data [J].

Antony, JH ;

Mertens, D ;

Dölle, A ;

Wasserscheid, P ;

Carper, WR .

CHEMPHYSCHEM, 2003, 4 (06) :588-594

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