Preparation and characterization of natural rubber latex/modified montmorillonite clay nano-composite

被引:18
作者
Al-Shemmari, Fayq Hsan Jabbar [1 ,2 ]
Rabah, Ali Abdelrahman [3 ]
Al-Mulla, Emad A. Jaffar [4 ]
Abd Alrahman, Nagi Osman Mohammed [1 ]
机构
[1] Sudan Univ Sci & Technol, Dept Chem Engn, Coll Engn, Khartoum, Sudan
[2] Baghdad Prov Council, Engn Consulting Bur, Baghdad, Iraq
[3] Univ Khartoum, Fac Engn, Dept Chem Engn, Khartoum, Sudan
[4] Univ Kufa, Dept Chem, Coll Sci, An Najaf 54001, Iraq
关键词
Natural rubber; Fatty amides; Modified montmorillonite; Nano-composites; NANOCOMPOSITES;
D O I
10.1007/s11164-012-0946-6
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this study, new biopolymer nano-composites have been prepared. Fatty amides (FAs) which were synthesized from palm olein, have been used as an organic compound to modify natural clay, sodium montmorillonite. The clay modification was carried out by stirring the clay particles in an aqueous solution of FAs by which the clay layer distance increases from 1.24 to 2.65 nm. The modified clay was then used in the preparation of the natural rubber (NR) nano-composite. The interaction of the modifier in the clay layer was characterized by ray diffraction (XRD), and Fourier transform infrared. The nano-composite was synthesized by melt blending of the modified clay and NR. The nano-composite was then characterized using XRD, transmission electron microscopy, thermogravimetric analysis (TGA), and tensile properties measurements. The XRD and transmission electron microscopy results confirmed the production of nano-composites. NR-modified clay nano-composites show higher thermal stability and significant improvement of mechanical properties in comparison with those of the pure NR.
引用
收藏
页码:4293 / 4301
页数:9
相关论文
共 16 条
[1]  
A.S.F.T.A. MATERIALS, 2004, D63803 ASTM
[2]  
Al-Mulla E.A.J., 2012, RES CHEM INTERMEDIAT, DOI [10.1007/s11164-012-0687-6, DOI 10.1007/S11164-012-0687-6]
[3]   Preparation of New Polymer Nanocomposites Based on Poly(lactic acid)/Fatty Nitrogen Compounds Modified Clay by a Solution Casting Process [J].
Al-Mulla, Emad A. Jaffar .
FIBERS AND POLYMERS, 2011, 12 (04) :444-450
[4]   Preparation of polylactic acid/epoxidized palm oil/fatty nitrogen compounds modified clay nanocomposites by melt blending [J].
Al-Mulla, Emad A. Jaffar .
POLYMER SCIENCE SERIES A, 2011, 53 (02) :149-157
[5]  
Al-Mulla EAJ, 2010, POLYM POLYM COMPOS, V18, P451
[6]   New biopolymer nanocomposites based on epoxidized soybean oil plasticized poly(lactic acid)/fatty nitrogen compounds modified clay: Preparation and characterization [J].
Al-Mulla, Emad A. Jaffar ;
Suhail, Adeel H. ;
Aowda, Saadon Abdulla .
INDUSTRIAL CROPS AND PRODUCTS, 2011, 33 (01) :23-29
[7]   Enzymatic Synthesis of Fatty Amides from Palm Olein [J].
Al-Mulla, Emad A. Jaffar ;
Yunus, Wan Md. Zin Wan ;
Ibrahim, Nor Azowa Bt ;
Rahman, Mohd Zaki A. .
JOURNAL OF OLEO SCIENCE, 2010, 59 (02) :59-64
[8]   Polylactic acid/epoxidized palm oil/fatty nitrogen compounds modified clay nanocomposites: Preparation and characterization [J].
Al-Mulla, Emad Abbas Jaffar .
KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2011, 28 (02) :620-626
[9]   Organo-montmorillonite as substitute of carbon black in natural rubber compounds [J].
Arroyo, M ;
López-Manchado, MA ;
Herrero, B .
POLYMER, 2003, 44 (08) :2447-2453
[10]   RUBBER-THERMOPLASTIC COMPOSITIONS .1. EPDM-POLYPROPYLENE THERMOPLASTIC VULCANIZATES [J].
CORAN, AY ;
PATEL, R .
RUBBER CHEMISTRY AND TECHNOLOGY, 1980, 53 (01) :141-150