Removal of Cr(VI) through calixarene based polymer inclusion membrane from chrome plating bath water

被引：139

作者：

Kaya, Ahmet ^{[1
]}

Onac, Canan ^{[1
]}

Alpoguz, H. Korkmaz ^{[1
]}

Yilmaz, Aydan ^{[2
]}

Atar, Necip ^{[3
]}

机构：

[1] Pamukkale Univ, Dept Chem, Denizli, Turkey

[2] Selcuk Univ, Dept Chem, Konya, Turkey

[3] Pamukkale Univ, Dept Chem Engn, Denizli, Turkey

来源：

CHEMICAL ENGINEERING JOURNAL | 2016年 / 283卷

关键词：

Chrome plating bath water; Polymer inclusion membrane; Calixarene; Transport of Cr(VI); Transport kinetics; SUPPORTED LIQUID-MEMBRANES; FACILITATED TRANSPORT; AQUEOUS-SOLUTIONS; DICHROMATE ANION; METAL-IONS; CARRIER; EXTRACTION; ACID; CHROMIUM(VI); COMPLEXES;

D O I：

10.1016/j.cej.2015.07.052

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

In this study, a calixarene based polymer inclusion membrane was employed for the removal of Cr(VI) from chrome plating bath water. The prepared polymer inclusion membrane was characterized by using Fourier transform infrared (FTIR) spectroscopy, atomic force microscopy (AFM) and contact angle measurements. The effects of carrier concentration, plasticizer type and temperature on the transport, the membrane's stability and thickness were examined. The transport efficiency of Cr(VI) using the polymer inclusion membrane was approximately 97.69%. The kinetic results demonstrated that Cr(VI) can be transported from the chrome plating bath water to the acceptor phase with high selective and efficiency. The experimental results showed the prepared polymer inclusion membrane (PIM) can be used effectively for the removal of Cr(VI) from the industrial wastewater. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：141 / 149

页数：9

共 35 条

[1] Recent trends in extraction and transport of metal ions using polymer inclusion membranes (PIMs) [J].