Versatility of the ionic assembling method to design highly luminescent PMMA nanocomposites containing [M6Qi8 La6]n- octahedral nano-building blocks

被引：56
作者：
Amela-Cortes, Maria [1 ,2 ]
Molard, Yann [1 ]
Paofai, Serge [1 ]
Desert, Anthony [1 ,3 ]
Duvail, Jean-Luc [3 ]
Naumov, Nikolay G. [4 ,5 ]
Cordier, Stephane [1 ]
机构：
[1] Univ Rennes 1, Inst Sci Chim Rennes, UR1 CNRS 6226, Grp Chim Solide & Mat, F-35042 Rennes, France
[2] SATT Ouest Valorisat, F-35708 Rennes, France
[3] Univ Nantes, CNRS, IMN, Inst Mat Jean Rouxel,UMR 6502, F-44322 Nantes, France
[4] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia
[5] Novosibirsk State Univ, Novosibirsk 630090, Russia
来源：
DALTON TRANSACTIONS | 2016年 / 45卷 / 01期
关键词：
TRANSITION-METAL CLUSTERS; ZNO QUANTUM DOTS; HYBRID MATERIALS; HEXARHENIUM(III) CLUSTERS; PHOTOPHYSICAL PROPERTIES; HEXANUCLEAR MOLYBDENUM; CHALCOGENIDE CLUSTERS; SOLUTION CHEMISTRY; HALIDE CLUSTERS; POLYMERS;
D O I：
10.1039/c5dt03734d
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
New luminescent poly(methylmethacrylate) (PMMA) nanocomposites with high content of different hexanuclear octahedral cluster building blocks, namely [Mo6I8(C2F5COO6)](2-), [Re6Se8(CN)(6)](4-) and [W6Cl14](2-) have been prepared by free-radical polymerisation. To do so, cluster complexes bearing a polymerisable ammonium counter-cation have been synthesised. In this way, we demonstrate that ionic assembling is a powerful tool to functionalise easily any type of anionic cluster units to be introduced in a PMMA organic matrix. All samples remain homogeneous, stable during several months, and retain the luminescence properties of the cluster precursor.
引用
收藏
页码：237 / 245
页数：9
相关论文
共 66 条
[1]   Assembly of hexam hexamolybdenum metallic clusters on silicon surfaces [J].
Ababou-Girard, S. ;
Cordier, S. ;
Fabre, B. ;
Molard, Y. ;
Perrin, C. .
CHEMPHYSCHEM, 2007, 8 (14) :2086-2090
[2]   Luminescence of salts and copolymers containing the (MoII6Cl8)4+ cluster [J].
Adamenko, OA ;
Loukova, GV ;
Smirnov, VA .
RUSSIAN CHEMICAL BULLETIN, 2002, 51 (06) :994-997
[3]   Synthesis, structure, and physicochemical properties of [Mo6Cl8]4+-containing clusters [J].
Adamenko, OA ;
Lukova, GV ;
Golubeva, ND ;
Smirnov, VA ;
Boiko, GN ;
Pomogailo, AD ;
Uflyand, IE .
DOKLADY PHYSICAL CHEMISTRY, 2001, 381 (1-3) :275-278
[4]   Tuned red NIR phosphorescence of polyurethane hybrid composites embedding metallic nanoclusters for oxygen sensing [J].
Amela-Cortes, Maria ;
Paofai, Serge ;
Cordier, Stephane ;
Folliot, Herve ;
Molard, Yann .
CHEMICAL COMMUNICATIONS, 2015, 51 (38) :8177-8180
[5]   Hexacyano octahedral metallic clusters as versatile building blocks in the design of extended polymeric framework and clustomesogens [J].
Amela-Cortes, Maria ;
Cordier, Stephane ;
Naumov, Nikolay G. ;
Meriadec, Cristelle ;
Artzner, Franck ;
Molard, Yann .
JOURNAL OF MATERIALS CHEMISTRY C, 2014, 2 (46) :9813-9823
[6]   Deep red luminescent hybrid copolymer materials with high transition metal cluster content [J].
Amela-Cortes, Maria ;
Garreau, Alexandre ;
Cordier, Stephane ;
Faulques, Eric ;
Duvail, Jean-Luc ;
Molard, Yann .
JOURNAL OF MATERIALS CHEMISTRY C, 2014, 2 (08) :1545-1552
[7]   Synthesis and Characterization of A4[Re6Q8L6]@SiO2 Red-Emitting Silica Nanoparticles Based on Re6 Metal Atom Clusters (A = Cs or K, Q = S or Se, and L = OH or CN) [J].
Aubert, Tangi ;
Ledneva, Alexandra Y. ;
Grasset, Fabien ;
Kimoto, Koji ;
Naumov, Nikolay G. ;
Molard, Yann ;
Saito, Noriko ;
Haneda, Hajime ;
Cordier, Stephane .
LANGMUIR, 2010, 26 (23) :18512-18518
[8]   Functional silica nanoparticles synthesized by water-in-oil microemulsion processes [J].
Aubert, Tangi ;
Grasset, Fabien ;
Mornet, Stephane ;
Duguet, Etienne ;
Cador, Olivier ;
Cordier, Stephane ;
Molard, Yann ;
Demange, Valerie ;
Mortier, Michel ;
Haneda, Hajime .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2010, 341 (02) :201-208
[9]   Lanthanide NIR luminescence for telecommunications, bioanalyses and solar energy conversion [J].
Buenzli, Jean-Claude G. ;
Eliseeva, Svetlana V. .
JOURNAL OF RARE EARTHS, 2010, 28 (06) :824-842
[10]   Polymer-stabilized gold nanoparticles and their incorporation into polymer matrices [J].
Corbierre, MK ;
Cameron, NS ;
Sutton, M ;
Mochrie, SGJ ;
Lurio, LB ;
Rühm, A ;
Lennox, RB .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (42) :10411-10412
1234567