1-Azaallylic anions in heterocyclic chemistry

被引：103
作者：
Mangelinckx, S [1 ]
Giubellina, N [1 ]
De Kimpe, N [1 ]
机构：
[1] Univ Ghent, Fac Agr & Appl Biol Sci, Dept Organ Chem, B-9000 Ghent, Belgium
来源：
CHEMICAL REVIEWS | 2004年 / 104卷 / 05期
关键词：
D O I：
10.1021/cr020084p
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
This review discloses relevant applications of the chemistry of 1-azaallylic anions leading to basic heterocycled systems such as aziridines, azetidines, pyrrolidines, pyrroles, piperdines, pyridines, oxiranes, oxolanes, ⋯ and higher functionalized rings, currently used in pharmaceutical chemistry and agrochemistry. First, structural information for 1-azaallylic preferences is given, followed by an overview of the different methods available for the synthesis of heterocycles of different ring sizes.
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页码：2353 / 2399
页数：47
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